The detection of magnetic fields with nanoscale resolution is a fundamental challenge for scanning probe magnetometry, biosensing, and magnetic storage. Current technologies based on giant magnetoresistance and tunneling magnetoresistance are limited at small sizes by thermal magnetic noise and spin-torque instability. These limitations do not affect Hall sensors consisting of high mobility semiconductors or metal thin films, but the loss of magnetic flux throughout the sensor's thickness greatly limits spatial resolution and sensitivity. Here we demonstrate graphene extraordinary magnetoresistance devices that combine the Hall effect and enhanced geometric magnetoresistance, yielding sensitivities rivaling that of state of the art sensors but do so with subnanometer sense layer thickness at the sensor surface. Back-gating provides the ability to control sensor characteristics, which can mitigate both inherent variations in material properties and fabrication-induced device-to-device variability that is unavoidable at the nanoscale.
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http://dx.doi.org/10.1021/nl903690y | DOI Listing |
Acc Chem Res
January 2025
Department of Chemistry, University of California, Berkeley, California 94720, United States.
ConspectusThe electronic properties of atomically thin van der Waals (vdW) materials can be precisely manipulated by vertically stacking them with a controlled offset (for example, a rotational offset─i.e., twist─between the layers, or a small difference in lattice constant) to generate moiré superlattices.
View Article and Find Full Text PDFNanoscale
January 2025
AIT Austrian Institute of Technology, Molecular Diagnostics, 1210 Vienna, Austria.
Metal nanoparticles are established tools for biomedical applications due to their unique optical properties, primarily attributed to localized surface plasmon resonances. They show distinct optical characteristics, such as high extinction cross-sections and resonances at specific wavelengths, which are tunable across the wavelength spectrum by modifying the nanoparticle geometry. These attributes make metal nanoparticles highly valuable for sensing and imaging in biology and medicine.
View Article and Find Full Text PDFSmart luminescent materials have drawn a significant attention owing to their unique optical properties and versatility in sensor applications. These materials, encompassing a broad spectrum of organic, inorganic, and hybrid systems including quantum dots, organic dyes, and metal-organic frameworks (MOFs), offer tunable emission characteristics that can be engineered at the molecular or nanoscale level to respond to specific stimuli, such as temperature, pH, and chemical presence. Recent advancements have been driven by the integration of nanotechnology, which enhances the sensitivity and selectivity of luminescent materials in sensor platforms.
View Article and Find Full Text PDFNano Lett
January 2025
Interdisciplinary Graduate Program in Materials Science, Vanderbilt University, Nashville, Tennessee 37235, United States.
Permeance-selectivity trade-offs are inherent to polymeric membranes. In fuel cells, thinner proton exchange membranes (PEMs) could enable higher proton conductance and increased power density with lower area-specific resistance (ASR), smaller ohmic losses, and lower ionomer cost. However, reducing thickness is accompanied by an increase in undesired species crossover harming performance and long-term efficiency.
View Article and Find Full Text PDFNanoscale
January 2025
Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085, India.
Sub-cellular organelle anomalies are frequently observed in diseases such as cancer. Early and precise diagnosis of these alterations can be crucial for patient outcomes. However, current diagnostic tools using conventional organic dyes or metal quantum dots face limitations, including poor biocompatibility, stringent storage conditions, limited solubility in aqueous media, and slow staining speeds.
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