Quantum Zeno effect in a model multilevel molecule.

J Phys Chem A

Istituto di Metodologie Inorganiche e dei Plasmi, Consiglio Nazionale delle Ricerche, Bari, Italy.

Published: December 2009

AI Article Synopsis

  • The research focuses on how a model molecule with two types of rotational energy levels behaves over time, particularly when these levels are connected by a constant interaction.
  • The rate at which populations relax between these energy levels depends on the frequency of molecular collisions in the surrounding gas.
  • This dependency is linked to the quantum Zeno effect, which is influenced by decoherence caused by the collisions of molecules.

Article Abstract

We study the dynamics of the populations of a model molecule endowed with two sets of rotational levels of different parity, whose ground levels are energetically degenerate and coupled by a constant interaction. The relaxation rate from one set of levels to the other one has an interesting dependence on the average collision frequency of the molecules in the gas. This is interpreted as a quantum Zeno effect due to the decoherence effects provoked by the molecular collisions.

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http://dx.doi.org/10.1021/jp9050512DOI Listing

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