A novel design strategy that extends metal-organic frameworks (MOFs) into tractable metallo-polymers was successfully explored by incorporating a homologous series of alkyl side chains to an organic linker, in which drastic solid to solid transformation is also observed.
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http://dx.doi.org/10.1039/b916092b | DOI Listing |
Nat Commun
December 2024
Department of Convergence IT Engineering, Pohang University of Science and Technology (POSTECH), Pohang, Republic of Korea.
Mid-infrared photoacoustic microscopy can capture biochemical information without staining. However, the long mid-infrared optical wavelengths make the spatial resolution of photoacoustic microscopy significantly poorer than that of conventional confocal fluorescence microscopy. Here, we demonstrate an explainable deep learning-based unsupervised inter-domain transformation of low-resolution unlabeled mid-infrared photoacoustic microscopy images into confocal-like virtually fluorescence-stained high-resolution images.
View Article and Find Full Text PDFNat Commun
December 2024
Department of Food Science, College of Agricultural and Life Sciences, Cornell University, Stocking Hall, Ithaca, NY, USA.
The rising demand for gold requires innovative methods for its recovery from e-waste. Here we present the synthesis of two tetrazine-based vinyl-linked covalent organic frameworks: TTF-COF and TPE-COF that adsorb gold ions and nanoparticles and catalyze the carboxylation of terminal alkynes. These covalent organic frameworks have low band gaps and high photocurrent responses.
View Article and Find Full Text PDFJ Environ Manage
December 2024
Business School, Hunan University, Changsha, 410082, Hunan, China. Electronic address:
Intervention policies play a crucial role in promoting the green transformation of consumption patterns and reducing consumer-side carbon emissions. This topic has been extensively explored by interdisciplinary scholars. However, these studies have not substantially improved our understanding of how intervention policies effectively encourage consumers to engage in green consumption.
View Article and Find Full Text PDFCurr Opin Chem Biol
December 2024
Department of Chemistry and Biochemistry, The Ohio State University, Columbus, OH 43210, USA; Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095, USA. Electronic address:
Enzymes catalyze molecular reactions with remarkable efficiency and selectivity under mild conditions. Photoactivated enzymes make use of a light-absorbing chromophore to drive chemical transformations, ideally using sunlight as an energy source. The direct attachment of a chromophore to native enzymes is advantageous, as information on the underlying catalytic mechanisms can be obtained.
View Article and Find Full Text PDFFront Public Health
December 2024
School of Economics and Management, Huainan Normal University, Huainan, China.
China's "14th Five-Year Plan" proposes the construction of a "Digital China," posing the challenge of digital transformation to coal mining enterprises. It is critical to compare the effectiveness of investing in digital devices with that of human capital. This study establishes a structural equation model based on the 'regulation-situation-behavior' theoretical framework.
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