We have combined the velocity map imaging technique with time-of-flight measurements to study the surface photochemistry of KBr single crystals. This approach yields 3-dimensional velocity distributions of Br atoms resulting from 193 nm photodesorption. The velocity distributions indicate that at least two non-thermal mechanisms contribute to the photodesorption dynamics. Our experimental geometry also allows us to measure the Br(2P3/2):Br(2P1/2) branching ratio, which is found to be 24:1.
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| http://dx.doi.org/10.1039/b909579a | DOI Listing |
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