Symmetries of the master equation and long-lived states of nuclear spins.

J Chem Phys

Sir Peter Mansfield Magnetic Resonance Centre, School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD, United Kingdom.

Published: November 2009

In terms of the master equation of relaxation, long-lived states in systems of n interacting spin-1/2 nuclei are described as those with eigenvalues much less than the characteristic T(1) rate. It is demonstrated that degeneracies of correlations between interacting dipole-dipole pairs are responsible for their presence. The case n=3 is considered in full detail.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.3265852DOI Listing

Publication Analysis

Top Keywords

master equation
8
long-lived states
8
symmetries master
4
equation long-lived
4
states nuclear
4
nuclear spins
4
spins terms
4
terms master
4
equation relaxation
4
relaxation long-lived
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!