AI Article Synopsis
- The paper presents a method for achieving highly selective Diels-Alder reactions using an acetylene equivalent, resulting in the formation of chiral-bridged dienes.
- These chiral-bridged dienes can coordinate with Rh(I), turning them into effective catalysts.
- The resulting catalysts facilitate the enantioselective addition of vinyl or aryl groups to alpha,beta-unsaturated ketones.
Article Abstract
This paper reports a method for highly enantioselective Diels-Alder reaction with an acetylene equivalent to produce chiral-bridged dienes. These dienes, by coordination to Rh(I), can serve as catalysts for the enantioselective addition of vinyl or aryl groups to alpha,beta-unsaturated ketones.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2814301 | PMC |
| http://dx.doi.org/10.1021/ol9025793 | DOI Listing |
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Catalytic enantioselective formation of chiral-bridged dienes which are themselves ligands for enantioselective catalysis.
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Article Synopsis
- The paper presents a method for achieving highly selective Diels-Alder reactions using an acetylene equivalent, resulting in the formation of chiral-bridged dienes.
- These chiral-bridged dienes can coordinate with Rh(I), turning them into effective catalysts.
- The resulting catalysts facilitate the enantioselective addition of vinyl or aryl groups to alpha,beta-unsaturated ketones.
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