We consider the influence of electric field gradients on the phase behavior of nonpolar binary mixtures. Small fields give rise to smooth composition profiles, whereas large enough fields lead to a phase-separation transition. The critical field for demixing as well as the equilibrium phase-separation interface are given as a function of the various system parameters. We show how the phase diagram in the temperature-composition plane is affected by electric fields, assuming a linear or nonlinear constitutive relations for the dielectric constant. Finally, we discuss the unusual case where the interface appears far from any bounding surface.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1063/1.3257688 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Density, Speed of Sound, Refractive Index, and the Derived Properties of Binary Mixtures of ,-Dimethylacetamide with 1-Butanol, 1-Pentanol, Furfural, or Furfuryl Alcohol at Different Temperatures.
J Chem Eng Data
January 2025
LATA2M, Laboratoire de Thermodynamique Appliquée et Modélisation Moléculaire, University of Tlemcen, Post Office Box 119, Tlemcen 13000, Algeria.
The density (ρ), speed of sound (), and refractive index ( ) of ,-dimethylacetamide (DMA) with 1-butanol, 1-pentanol, furfural (FFL), or furfuryl alcohol (FA) as a function of composition and at = 293.15 to 323.15 K with an interval of 10 K and atmospheric pressure were measured.
View Article and Find Full Text PDFDensity and Viscosity of CO-Loaded Aqueous 2-Amino-2-methyl-1-propanol (AMP) and Piperazine (PZ) Mixtures.
J Chem Eng Data
January 2025
Department of Chemical Engineering, Norwegian University of Science and Technology, Trondheim N-7491, Norway.
Densities and viscosities of aqueous 2-amino-2-methyl-1-propanol (AMP)/piperazine (PZ) solutions with and without CO are measured from 20 to 80 °C at ambient pressure. Redlich-Kister-based correlations are proposed for the excess molar volumes and viscosity deviation of the binary and ternary mixtures. Empirical correlations are developed to quantitatively describe the effect of CO on the density and viscosity of the aqueous AMP/PZ solutions.
View Article and Find Full Text PDFSpeed of Sound Measurements of R-1130(E) and an Azeotropic Blend of R-1336mzz(Z)/1130(E).
Int J Thermophys
January 2024
Applied Chemicals and Materials Division, National Institute of Standards and Technology, Boulder, CO 80305, USA.
Sound speed data measured using a dual-path pulse-echo instrument are reported for pure -1,2-dichloroethene (R-1130(E)) and an azeotropic blend of -1,1,1,4,4,4-hexafluorobutene (R-1336mzz(Z)) and R-1130(E) with a composition of 74.8 mass % R-1336mzz(Z) with the balance being R-1130(E). The azeotropic blend of R-1336mzz(Z)/1130(E) is classified as R-514A in ANSI/ASHRAE standard 34.
View Article and Find Full Text PDFA Lewis basic site rich metal-organic framework featuring a hydrogen-bonded acetylene nano-trap for the efficient separation of CH/CO.
Dalton Trans
January 2025
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi Province, China.
The physical separation of CH from CO on metal-organic frameworks (MOFs) has received a substantial amount of research interest due to its advantages of simplicity, security, and energy efficiency. However, the exploitation of ideal MOF adsorbents for CH/CO separation remains a challenging task due to their similar physical properties and molecular sizes. Herein, we report a unique CH nano-trap constructed using accessible oxygen and nitrogen sites, which exhibits energetic favorability toward CH molecules.
View Article and Find Full Text PDFEnvironmentally tolerant multifunctional eutectogel for highly sensitive wearable sensors.
Mater Horiz
January 2025
Institute of Biomedical Engineering, College of Medicine, Southwest Jiaotong University, Chengdu 610031, China.
Article Synopsis
- Flexible hydrogel sensors have limitations in sensitivity and freezing in low temperatures, hindering their applications.
- A new multifunctional eutectogel is developed through photopolymerization, offering properties like high transparency, anti-freezing, and self-healing.
- This eutectogel shows exceptional performance with a high gauge factor for strain sensitivity, making it promising for flexible electronics in cold conditions.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!