Synthesis and characterization of Mn-MCM-41--its catalytic activity for the synthesis of carbon nanotubes.

J Nanosci Nanotechnol

Department of Chemistry and Center for Nanoscience and Nanotechnology, Anna University, Chennai 600025, India.

Published: September 2009

Mn-MCM-41 was synthesized in various (Si/Mn = 25, 50, 75 and 100) ratios, using manganese acetate as source for manganese by hydrothermal method and was calcined at 550 degrees C for 6 hrs. The physico-chemical characterizations of Mn-MCM-41 showed the formation of hexagonally arranged mesopores with high surface area. The calcined Mn-MCM-41 was used as catalytic templates for the growth of large amount of carbon nanotubes. Acetylene was used as carbon source and nitrogen as carrier gas for the formation of carbon nanotubes by chemical vapor deposition method. The effect of temperature was carried out 750, 800, 850 and 900 degrees C, at a flow rate of 40 ml/min of acetylene precursor. The SEM, TEM and XRD confirmed the formation of large amount of carbon nanotubes.

Download full-text PDF

Source
http://dx.doi.org/10.1166/jnn.2009.1187DOI Listing

Publication Analysis

Top Keywords

carbon nanotubes
16
large amount
8
amount carbon
8
carbon
5
synthesis characterization
4
characterization mn-mcm-41--its
4
mn-mcm-41--its catalytic
4
catalytic activity
4
activity synthesis
4
synthesis carbon
4

Similar Publications

To study the enhancement effect of carbon nanotubes (CNTs) on the splitting tensile properties of foamed concrete backfill in which cement and fly ash were used as the cementitious materials and natural sand was used as the aggregate, specimens of CNT-modified foamed concrete backfill were prepared. Brazilian splitting tests were used to investigate the splitting tensile strength of the CNT-modified foamed concrete backfill, and the digital speckle correlation method was used to analyze the stress field characteristics and crack expansion law of the specimens during splitting tensile testing. The stress-strain characteristics and energy dissipation laws of the backfill were studied at various static loading rates, and a relationship between the splitting tensile strength, ultimate strain, and loading rate was established.

View Article and Find Full Text PDF

Strain sensing fabrics are able to sense the deformation of the outside world, bringing more accurate and real-time monitoring and feedback to users. However, due to the lack of clear sensing mechanism for high sensitivity and high linearity carbon matrix composites, the preparation of high performance strain sensing fabric weaving is still a major challenge. Here, an elastic polyurethane(PU)-based conductive fabric(GCPU) with high sensitivity, high linearity and good hydrophobicity is prepared by a novel synergistic conductive network strategy.

View Article and Find Full Text PDF

Construction of an electrochemical sensor for the detection of methyl parathion with three-dimensional graphdiyne-carbon nanotubes.

Mikrochim Acta

January 2025

CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China.

To enhance the application performance of graphdiyne (GDY) in electrochemical sensing, carbon nanotubes (CNTs) were grown in situ to construct three-dimensional nanoarchitectures of GDY-CNTs composites. GDY-CNTs showed superior electrochemical properties and detection response to MP when compared with GDY, as the in situ growth of CNTs significantly increased the electrode surface area and enhanced the electron transfer process. GDY-CNTs were successfully used to construct electrochemical sensors for methyl parathion (MP).

View Article and Find Full Text PDF

In this work, we describe a computational tool designed to determine the local dielectric constants (ε) of charge-neutral heterogeneous systems by analyzing dipole moment fluctuations from molecular dynamics (MD) trajectories. Unlike conventional methods, our tool can calculate dielectric constants for dynamically evolving selections of molecules within a defined region of space, rather than for fixed sets of molecules. We validated our approach by computing the dielectric constants of TIP3P water nanospheres, achieving results consistent with literature values for bulk water.

View Article and Find Full Text PDF

Bioinspired Photo-Thermal Catalytic System using Covalent Organic Framework-based Aerogel for Synchronous Seawater Desalination and H2O2 Production.

Angew Chem Int Ed Engl

January 2025

Nankai University, School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, CHINA.

Efficient utilization of solar energy is widely regarded as a crucial solution to addressing the energy crisis and reducing reliance on fossil fuels. Coupling photothermal and photochemical conversion can effectively improve solar energy utilization yet remains challenging. Here, inspired by the photosynthesis system in green plants, we report herein an artificial solar energy converter (ASEC) composed of light-harvesting units as solar collector and oriented ionic hydrophilic channels as reactors and transporters.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!