Mn-MCM-41 was synthesized in various (Si/Mn = 25, 50, 75 and 100) ratios, using manganese acetate as source for manganese by hydrothermal method and was calcined at 550 degrees C for 6 hrs. The physico-chemical characterizations of Mn-MCM-41 showed the formation of hexagonally arranged mesopores with high surface area. The calcined Mn-MCM-41 was used as catalytic templates for the growth of large amount of carbon nanotubes. Acetylene was used as carbon source and nitrogen as carrier gas for the formation of carbon nanotubes by chemical vapor deposition method. The effect of temperature was carried out 750, 800, 850 and 900 degrees C, at a flow rate of 40 ml/min of acetylene precursor. The SEM, TEM and XRD confirmed the formation of large amount of carbon nanotubes.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1166/jnn.2009.1187 | DOI Listing |
Sci Rep
January 2025
School of City and Architecture Engineering, Zaozhuang University, Zaozhuang, 277160, Shandong, China.
To study the enhancement effect of carbon nanotubes (CNTs) on the splitting tensile properties of foamed concrete backfill in which cement and fly ash were used as the cementitious materials and natural sand was used as the aggregate, specimens of CNT-modified foamed concrete backfill were prepared. Brazilian splitting tests were used to investigate the splitting tensile strength of the CNT-modified foamed concrete backfill, and the digital speckle correlation method was used to analyze the stress field characteristics and crack expansion law of the specimens during splitting tensile testing. The stress-strain characteristics and energy dissipation laws of the backfill were studied at various static loading rates, and a relationship between the splitting tensile strength, ultimate strain, and loading rate was established.
View Article and Find Full Text PDFNanotechnology
January 2025
Anhui Agricultural University, Hefei, 230036, P. R. China, Hefei, 230036, CHINA.
Strain sensing fabrics are able to sense the deformation of the outside world, bringing more accurate and real-time monitoring and feedback to users. However, due to the lack of clear sensing mechanism for high sensitivity and high linearity carbon matrix composites, the preparation of high performance strain sensing fabric weaving is still a major challenge. Here, an elastic polyurethane(PU)-based conductive fabric(GCPU) with high sensitivity, high linearity and good hydrophobicity is prepared by a novel synergistic conductive network strategy.
View Article and Find Full Text PDFMikrochim Acta
January 2025
CAS Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049, China.
To enhance the application performance of graphdiyne (GDY) in electrochemical sensing, carbon nanotubes (CNTs) were grown in situ to construct three-dimensional nanoarchitectures of GDY-CNTs composites. GDY-CNTs showed superior electrochemical properties and detection response to MP when compared with GDY, as the in situ growth of CNTs significantly increased the electrode surface area and enhanced the electron transfer process. GDY-CNTs were successfully used to construct electrochemical sensors for methyl parathion (MP).
View Article and Find Full Text PDFJ Chem Theory Comput
January 2025
Department of Chemistry and Biochemistry, The University of Texas at El Paso, El Paso, Texas 79968, United States.
In this work, we describe a computational tool designed to determine the local dielectric constants (ε) of charge-neutral heterogeneous systems by analyzing dipole moment fluctuations from molecular dynamics (MD) trajectories. Unlike conventional methods, our tool can calculate dielectric constants for dynamically evolving selections of molecules within a defined region of space, rather than for fixed sets of molecules. We validated our approach by computing the dielectric constants of TIP3P water nanospheres, achieving results consistent with literature values for bulk water.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Nankai University, School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, CHINA.
Efficient utilization of solar energy is widely regarded as a crucial solution to addressing the energy crisis and reducing reliance on fossil fuels. Coupling photothermal and photochemical conversion can effectively improve solar energy utilization yet remains challenging. Here, inspired by the photosynthesis system in green plants, we report herein an artificial solar energy converter (ASEC) composed of light-harvesting units as solar collector and oriented ionic hydrophilic channels as reactors and transporters.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!