Unusual regiodivergence in metal-catalysed intramolecular cyclisation of gamma-allenols.

Chem Commun (Camb)

Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London SW7 2AZ, UK.

Published: December 2009

Different O-heterocycles can be obtained from a common gamma-allenol precursor by using Ag, Zn or Sn catalysts; the results were rationalised by molecular modelling.

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Source
http://dx.doi.org/10.1039/b913295cDOI Listing

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