Influence of nanocrystalline boron precursor powder on superconductivity in MgB2 bulk.

J Nanosci Nanotechnol

Institute for Superconducting and Electronic Materials, University of Wollongong, Northfields Ave., Wollongong, NSW 2522, Australia.

Published: December 2009

In this report, high-purity nanocrystalline boron powders processed by ball-milling were used as the precursor powders to fabricate MgB2 superconductor. The transport properties and the critical current density in the samples made from ball-milled boron powders and as-supplied boron powders were investigated. It was found that the ball-milled boron powders led to a significant enhancement of the critical current density in MgB2 sintered at 650 degrees C. The reason can be attributed to the small MgB2 grain size caused by the ball-milled boron precursor powders. The resistivity of the samples made from the ball-milled boron powder was lower than that of the sample from as-supplied boron powder. As the sintering temperature increased, both resistivity and upper critical field decreased in the samples using the ball-milled boron powders as a precursor. Poor connectivity and large strain are responsible for the high resistivity.

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http://dx.doi.org/10.1166/jnn.2009.1764DOI Listing

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