Lignocellulosic materials can significantly contribute to the development of biobased composites. In this work, glyoxal-phenolic resins for composites were prepared using glyoxal, which is a dialdehyde obtained from several natural resources. The resins were characterized by (1)H, (13)C, 2D, and (31)P NMR spectroscopies. Resorcinol (10%) was used as an accelerator for curing the glyoxal-phenol resins in order to obtain the thermosets. The impact-strength measurement showed that regardless of the cure cycle used, the reinforcement of thermosets by 30% (w/w) sisal fibers improved the impact strength by one order of magnitude. Curing with cycle 1 (150 degrees C) induced a high diffusion coefficient for water absorption in composites, due to less interaction between the sisal fibers and water. The composites cured with cycle 2 (180 degrees C) had less glyoxal resin coverage of the cellulosic fibers, as observed by images of the fractured interface observed by SEM. This study shows that biobased composites with good properties can be prepared using a high proportion of materials obtained from natural resources.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.biortech.2009.10.005 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Estimation of PHA concentrations from cell density data in Cupriavidus necator.
Appl Microbiol Biotechnol
January 2025
Process Synthesis and Process Dynamics, Max Planck Institute for Dynamics of Complex Technical Systems, Magdeburg, Germany.
The production of biodegradable and biobased polymers is one way to overcome the present plastic pollution while using cheap and abundant feedstocks. Polyhydroxyalkanoates are a promising class of biopolymers that can be produced by various microorganisms. Within the production process, batch-to-batch variation occurs due to changing feedstock composition when using waste streams, slightly different starting conditions, or biological variance of the microorganisms.
View Article and Find Full Text PDFPlasma-Activated Water/Ultrasound as a Green Method to Modify Wood Fiber By-Product: Insights of Their Mechanical Performance in Polylactic Acid-Based Biofilms.
Biopolymers
March 2025
Centro de Investigación en Química Aplicada, Saltillo, Coahuila, Mexico.
Exploring new ecological and simultaneous processes to modify wood fibers (WF) by-products is a required pathway toward circular economy and sustainability. Thus, plasma-activated water (PAW) and ultrasound (U) were employed as alternative methods to modify WF in a continuous process. Such treatments promoted the etching and cavities on the WF surface that destabilized the hydrogen bonds of the hemicellulose and lignin molecules, increasing the cellulose fraction.
View Article and Find Full Text PDFEvaluation of biobased materials in the development of polymeric membranes for water capture and purification.
Int J Biol Macromol
January 2025
Departamento de Ingeniería Química, Facultad de Química, Universidad de Sevilla, 41012 Sevilla, Spain.
The current study addresses the pressing issue of unsustainable water management, particularly in regions experiencing high water stress. It focuses on examining the viability of polymeric membranes composed of biobased materials, mainly chitosan, for various sustainable water management solutions. The membranes evaluated in the study were blends of PVC with either chitosan-silica or charcoal-silica, designed to enhance their functionality and performance.
View Article and Find Full Text PDFLignin reinforced eco-friendly and functional nanoarchitectonics materials with tailored interfacial barrier performance.
J Colloid Interface Sci
January 2025
State Key Laboratory of Biobased Fiber Manufacturing Technology, China Light Industry Key Laboratory of Papermaking and Biorefinery, Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Tianjin 300457, China. Electronic address:
Exploring innovative and sustainable routes for the production of biodegradable biomass-based materials is critical to promote a circular carbon economy and carbon neutrality goals. Fossil-based non-biodegradable plastic waste poses a nonnegligible threat to humans and the ecological environment, and biomass-based functional materials are becoming increasingly viable alternatives. Lignin, a naturally occurring macromolecular polymer, is green and renewable resource rich in aromatic rings, with biodegradability, biocompatibility, and excellent processability for eco-friendly composites.
View Article and Find Full Text PDFNanocellulose composites based on embedded europium-containing coordination polymers for the detection of antibiotics.
Int J Biol Macromol
January 2025
State Key Laboratory of Biobased Fiber Manufacturing Technology, Tianjin University of Science and Technology, Tianjin 300457, PR China; Tianjin Key Laboratory of Pulp and Paper, Tianjin University of Science and Technology, Tianjin 300457, PR China; China Light Industry Key Laboratory of Papermaking and Biorefinery, Tianjin University of Science and Technology, Tianjin 300457, PR China. Electronic address:
Developing sensitive and reliable methods for detecting antibiotics in water solutions is essential for protecting public health and the environment. Here, we report a novel fluorescent film with superior mechanical properties and detection response to ciprofloxacin (CIP), achieved through the in-situ growth of europium-based metal-organic frameworks on TEMPO-oxidized cellulose nanofibrils (TOCNF). Firstly, Eu(III) and 2,6-pyridinedicarboxylic acid (DPA) served as precursors, and a simple self-assembly strategy was employed to grow the composite film material (Eu-DPA@TOCNF) in situ on TOCNF, which exhibited characteristic emission peaks.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!