A one-pot, pseudo four-component method for the efficient and simple synthesis of spiro[diindeno[1,2-b:2',1'-e]pyridine-11,3'-indoline]-2',10,12-trione derivatives in refluxing acetonitrile is reported. The features of this procedure are mild reaction conditions, high yields of products, and operational simplicity.

Download full-text PDF

Source
http://dx.doi.org/10.1021/cc900130aDOI Listing

Publication Analysis

Top Keywords

one-pot pseudo
8
pseudo four-component
8
four-component synthesis
4
synthesis spiro[diindeno[12-b2'1'-e]pyridine-113'-indoline]-trione
4
spiro[diindeno[12-b2'1'-e]pyridine-113'-indoline]-trione library
4
library one-pot
4
four-component method
4
method efficient
4
efficient simple
4
simple synthesis
4

Similar Publications

ZnCl-doped mesoporous silica nanoparticles prepared via a simple one-pot method for highly efficient nitrate removal.

Environ Res

December 2024

Integrated Science and Technology Research Center, Faculty of Technology and Environment, Prince of Songkla University, Phuket Campus, Kathu, Phuket, 83120, Thailand. Electronic address:

Nitrate is a crucial nutrient in the natural nitrogen cycle. However, human activities have elevated nitrate levels in aquatic ecosystems beyond natural thresholds, posing risks to human health and the environment. In this work, ZnCl-doped mesoporous silica nanoparticles (ZnCl@MSN) were synthesized using a one-pot preparation method, leading to a streamlined process with reduced time and energy consumption.

View Article and Find Full Text PDF

Mechanisms of enhanced Cr (VI) removal by waste lignin derived N-doped hierarchical porous carbon (N-HPC).

Chemosphere

December 2024

State Environmental Protection Key Laboratory of Efficient Utilization Technology of Coal Waste Resources, Institute of Resources and Environmental Engineering, Shanxi University, Taiyuan 030006, P. R. China.

N-doped hierarchical porous carbon (N-HPC) is made from waste lignin by a one-pot method, and its mechanisms of Cr (VI) removal was investigated. The specific surface area (S) of N-HPC-Fe3 was 1749.8 m/g, the experimentally determined equilibrium adsorption capacity (q) for Cr (VI) was 386.

View Article and Find Full Text PDF

Water contamination by nitro compounds from various industrial processes has significantly contributed to environmental pollution and severely threatened aquatic ecosystems. Inexpensive, efficient, and environmentally benign catalysts are required for the catalytic reduction of such nitro compounds. This study reports the fabrication of various nanocomposites (NCs) of copper oxide nanoparticles (CuO NPs) supported on a kaolin sheet using straightforward and simple one-pot synthesis procedures that control the metal precursor to kaolin ratios.

View Article and Find Full Text PDF

Among the nucleophilic oxidants employed in the gold-catalysed oxidation of alkynes, sulphur-based reagents have played a substantial role since the beginning, granting access to the respective gold carbene intermediates. Herein, we describe the first example of the substance class of sulfoximines being used as atom transfer reagents to alkynes in gold catalysis. Based on the transformation of N-(2-alkynylphenyl) sulfoximines to 3H-indol-3-ones, it is demonstrated that the sulfoximine functionality is capable of selectively transferring first its nitrogen moiety to the alkyne, forming the α-imino gold carbene, which is then oxidised by the released sulfoxide moiety in a second step via a pseudo-intramolecular mechanism - a distinctive feature that differentiates this work mechanistically from earlier studies.

View Article and Find Full Text PDF

In this study, we report the synthesis and full characterization of five novel ruthenium(II) cymene complexes with the general formula [Ru(cym)(L')Cl], featuring N,O- and N,N-coordinating pyrazolone-based hydrazone ligands. We have characterized these complexes using single X-ray crystallography, Fourier-transform infrared spectroscopy (FT-IR), Nuclear magnetic resonance (NMR), elemental analysis, and Electrospray Ionization Mass Spectroscopy (ESI-MS). Crystallographic analysis confirmed that all of the complexes have a similar type of half-sandwich, pseudo-octahedral "three-legged piano-stool" geometry where the cymene moiety displays the typical η-coordination mode and the hydrazone ligands coordinate to the Ru(II) center in a bidentate fashion.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!