The carbon dioxide (CO2) removal efficiency, reaction rate, and CO2 loading into aqueous blended monoethanolamine (MEA) + 2-amino-2-methyl-1-propanol (AMP) solutions to enhance absorption characteristics of MEA and AMP were carried out by the absorption/regeneration process. As a result, compared to aqueous MEA and AMP solutions, aqueous blended MEA + AMP solutions have a higher CO2 loading than MEA and a higher reaction rate than AMP. The CO2 loading of rich amine of aqueous 18 wt.% MEA + 12 wt.% AMP solution was 0.62 mol CO2/mol amine, which is 51.2% more than 30 wt.% MEA (0.41 mol CO2/mol amine). Consequently, blending MEA and AMP could be an effective way to design considering economical efficiency and used to operate absorber for a long time.

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http://dx.doi.org/10.1016/s1001-0742(08)62360-8DOI Listing

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  • * A new ion chromatography method was developed to analyze multiple organic amines simultaneously without complex preparation, using specific conditions to enhance separation efficiency.
  • * The method showed excellent accuracy with high linear correlation for the eight tested amines, having low detection limits and good recovery rates, indicating it could reliably be used for analyzing desulfurization solutions.
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