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Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters. | LitMetric

Access to new magnetic cores in Fe(III) and Fe(III)/Cu(II) spin clusters.

Dalton Trans

WestCHEM, Department of Chemistry, University of Glasgow, University Avenue, UK G12 8QQ.

Published: November 2009

AI Article Synopsis

  • The report discusses the synthesis and structural analysis of two iron complexes: [Fe(14)O(4)(OH)(4)(H(2)L)(2)(HL)(4)(piv)(20)] and [Fe(8)Cu(2)O(4)(H(2)L)(4)(HL)(2)(OBz)(12)].
  • Both complexes feature distinct core structures that contribute to their properties.
  • Notably, they exhibit non-zero spin ground states, indicating interesting magnetic characteristics.

Article Abstract

The synthesis, structure and magnetic properties of [Fe(14)O(4)(OH)(4)(H(2)L)(2)(HL)(4)(piv)(20)] (1) and [Fe(8)Cu(2)O(4)(H(2)L)(4)(HL)(2)(OBz)(12)] (2) are reported (H(3)L = 2-amino-2-(hydroxymethyl)propane-1,3-diol): both complexes have unique core structures and display non-zero spin ground states.

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Source
http://dx.doi.org/10.1039/b913102gDOI Listing

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