Particles are often too small to be separated from a reaction system and recycled, especially in wastewater treatment via a catalytic ozonation process. Thus, the objective of this study was to prepare a magnetic catalyst (SiO(2)/Fe(3)O(4)) that can be recycled by using an external magnetic field. The effects of the characteristics of the magnetic catalyst, pH values, catalyst dosage, and initial concentration of Reactive Black 5 (RB5) on mineralization efficiency of the magnetic catalyst/H(2)O(2)/O(3) process were also investigated. The mineralization efficiency of RB5 under various conditions followed the sequence: SiO(2)/Fe(3)O(4)/H(2)O(2)/O(3)>SiO(2)/Fe(3)O(4)/O(3)>Fe(3)O(4)/O(3) approximately H(2)O(2)/O(3)>O(3)>SiO(2)/Fe(3)O(4)/H(2)O(2). Given the results of our reuse and recovery experiments, the magnetic catalyst shows considerable promise for use in water treatment.
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http://dx.doi.org/10.1016/j.jhazmat.2009.09.122 | DOI Listing |
Nat Commun
January 2025
Faculty of Physics, Astronomy and Applied Computer Science, Jagiellonian University, PL 30-348, Krakow, Poland.
Atomically precise synthesis of graphene nanostructures on semiconductors and insulators has been a formidable challenge. In particular, the metallic substrates needed to catalyze cyclodehydrogenative planarization reactions limit subsequent applications that exploit the electronic and/or magnetic structure of graphene derivatives. Here, we introduce a protocol in which an on-surface reaction is initiated and carried out regardless of the substrate type.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Department of Chemistry and Biochemistry, University of California, 1156 High Street, Santa Cruz, California, 95064, USA.
Development of high-performance electrocatalysts for water splitting is crucial for a sustainable hydrogen economy. In this study, rapid heating of ruthenium(III) acetylacetonate by magnetic induction heating (MIH) leads to the one-step production of Ru-RuO₂/C nanocomposites composed of closely integrated Ru and RuO₂ nanoparticles. The formation of Mott-Schottky heterojunctions significantly enhances charge transfer across the Ru-RuO interface leading to remarkable electrocatalytic activities toward both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in 1 m KOH.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry, Panskura Banamali College, Panskura RS, WB 721152, India.
The coordination compounds featuring a {CuO} core, typically bridged by hydroxo or alkoxo groups, are particularly intriguing due to their notable magnetic properties and catalytic activity. In this study, we explored the synthesis and characterization of four new Schiff base ligands and their subsequent complexation with Cu salts, which resulted in the formation of three tetranuclear complexes: [Cu(L)]·2HO (1), [Cu(L)(HL)](Cl)(NO)·5HO (2), and [Cu(L)] (3), as well as one dinuclear complex: [Cu(L)] (4). These tetranuclear complexes all feature a {CuO} core, but with differing coordination environments around the Cu centers.
View Article and Find Full Text PDFNanoscale Adv
December 2024
Organic and Nano Group (ONG), Department of Chemistry, Iran University of Science and Technology (IUST) PO Box 16846-13114 Tehran Iran
A magnetic-biopolymer composite of carboxymethyl cellulose (CMC), designated as FeO@CMC, was synthesized featuring remarkable stability and an active surface with a green biosynthetic method. This composite was engineered to serve as a substrate for stabilizing silver nanoparticles (Ag NPs) with enhanced functional properties. The catalytic efficacy of the nanocatalyst, incorporating Ag NPs at concentrations of 3%, 7%, and 10%, was evaluated for the reduction of the toxic compound 4-nitrophenol to the beneficial 4-aminophenol.
View Article and Find Full Text PDFInorg Chem
January 2025
State Key Laboratory of Molecular & Process Engineering, SINOPEC Research Institute of Petroleum Processing, Beijing 100083, China.
The ZSM-5 zeolite is the key active component in high-severity fluid catalytic cracking (FCC) catalysts and is routinely activated by phosphorus compounds in industrial production. To date, however, the detailed structure and function of the introduced phosphorus still remain ambiguous, which hampers the rational design of highly efficient catalysts. In this work, using advanced solid-state NMR techniques, we have quantitatively identified a total of seven types of P-containing complexes in P-modified ZSM-5 zeolite and clearly revealed their structure, location, and catalytic role.
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