Chapman-Enskog expansion for multi-particle collision models.

Phys Chem Chem Phys

Department of Physics, North Dakota State University, P.O. Box 6050, Fargo, ND 58108, USA.

Published: November 2009

Particle-based simulation methods for fluid flow follow a discrete time dynamics of subsequent streaming and collision events. The algorithm considered here, called stochastic rotation dynamics, involves collisions between an arbitrary number of partners; all particles that happen to be in the same cell of a randomly positioned grid interact at once by prescribed rules. I show, in two dimensions, how a multi-particle generalization of the Enskog equation can be derived from the Liouville equation and how the hydrodynamic equations can be obtained by a Chapman-Enskog expansion. The resulting macroscopic equations contain a collisional contribution to the transport coefficients, absent in earlier Chapman-Enskog approaches, which agrees exactly with previously known results from other kinetic theories. This approach opens up a powerful, systematic route to deriving hydrodynamic equations for particle-based models, which is generalizable to models with active particles.

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Source
http://dx.doi.org/10.1039/b910356bDOI Listing

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