Carbon nanotube (CNT) adsorption technology has the potential to support point of use (POU) based treatment approach for removal of bacterial pathogens, natural organic matter (NOM), and cyanobacterial toxins from water systems. Unlike many microporous adsorbents, CNTs possess fibrous shape with high aspect ratio, large accessible external surface area, and well developed mesopores, all contribute to the superior removal capacities of these macromolecular biomolecules and microorganisms. This article provides a comprehensive review on application of CNTs as adsorbent media to concentrate and remove pathogens, NOM, and cyanobacterial (microcystin derivatives) toxins from water systems. The paper also surveys on consideration of CNT based adsorption filters for removal of these contaminants from cost, operational and safety standpoint. Based on the studied literature it appears that POU based CNT technology looks promising, that can possibly avoid difficulties of treating biological contaminants in conventional water treatment plants, and thereby remove the burden of maintaining the biostability of treated water in the distribution systems.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1016/j.scitotenv.2009.09.027 | DOI Listing |
Acc Chem Res
January 2025
The Department of Chemistry, State University of New York at Binghamton, Binghamton, New York 13902, United States.
ConspectusIn the search for efficient and selective electrocatalysts capable of converting greenhouse gases to value-added products, enzymes found in naturally existing bacteria provide the basis for most approaches toward electrocatalyst design. Ni,Fe-carbon monoxide dehydrogenase (Ni,Fe-CODH) is one such enzyme, with a nickel-iron-sulfur cluster named the C-cluster, where CO binds and is converted to CO at high rates near the thermodynamic potential. In this Account, we divide the enzyme's catalytic contributions into three categories based on location and function.
View Article and Find Full Text PDFbioRxiv
January 2025
Chemical and Biological Engineering - Iowa State University, 618 Bissell Rd, Ames, IA 50011.
Proteins can be rapidly prototyped with cell-free expression (CFE) but in most cases there is a lack of probes or assays to measure their function directly in the cell lysate, thereby limiting the throughput of these screens. Increased throughput is needed to build standardized, sequence to function data sets to feed machine learning guided protein optimization. Herein, we describe the use of fluorescent single-walled carbon nanotubes (SWCNT) as effective probes for measuring protease activity directly in cell-free lysate.
View Article and Find Full Text PDFPNAS Nexus
January 2025
Department of Chemistry, New York University, 100 Washington Square East, New York, NY 10003, USA.
DNA has found increasing applications in molecular engineering, yet its chiral property has rarely been utilized. Here, we report a mirror-image experiment using naturally occurring D-DNA and its enantiomer L-DNA to sort a chiral mixture of single-wall carbon nanotubes (SWCNTs). We find that parity conservation leads to a robust experimental outcome: changing DNA chirality results in handedness inversion of the purified nanotube.
View Article and Find Full Text PDFInd Eng Chem Res
January 2025
Department of Chemistry, Physics, and Materials Science, Fayetteville State University, Fayetteville, North Carolina 28301, United States.
An efficient Suzuki cross-coupling reaction under continuous flow conditions was developed utilizing an immobilized solid supported catalyst consisting of bimetallic nickel-palladium nanoparticles (Ni-Pd/MWCNTs). In this process, the reactants can be continuously pumped into a catalyst bed at a high flow rate of 0.6 mL/min and the temperature of 130 °C while the Suzuki products are recovered in high steady-state yields for prolonged continuous processing.
View Article and Find Full Text PDFACS Omega
January 2025
School of Chemical Engineering, Vellore Institute of Technology, Vellore, Tamil Nadu 632014, India.
This work explores the enhancement of EMI shielding efficiency of polyurethane (PU) foam by loading multiwall carbon nanotube (MWCNTs)-decorated hollow glass microspheres (HGMs). MWCNT was coated onto the HGM surface by a simple solution casting technique. The coated HGM particles were loaded in PU foams, resulting in an even dispersion of MWCNT in the foam struts, thereby forming an interconnected conductive network in the polymer matrix.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!