We employed the atomic layer deposition technique to grow Al(2)O(3) films with nominal thicknesses of 400, 300, and 200 nm on silicon and soda lime glass substrates. The optical properties of the films were investigated by measuring reflection spectra in the 400-1800 nm wavelength range, followed by numerical fitting assuming the Sellmeier formula for the refractive index of Al(2)O(3). The films grown on glass substrates possess higher refractive indices as compared to the films on silicon. Optical waveguiding is demonstrated, confirming the feasibility of high-index contrast planar waveguides fabricated by atomic layer deposition.
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http://dx.doi.org/10.1364/AO.48.005407 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
State Key Laboratory of Intelligent Manufacturing Equipment and Technology, School of Mechanical Science and Engineering, Huazhong University of Science and Technology, Wuhan, Hubei 430074, People's Republic of China.
The Ni-rich LiNiCoMnO cathode (NCM, ≥ 0.6) suffers rapid capacity decay due to serious surface degradations from the corrosion of the electrolyte. The processes of the HO- and O-based AlO atomic layer deposition (ALD) on the single-crystal LiNiCoMnO (NCM83) are investigated by measurements to understand the mechanism of their different impacts on the electrochemical performance of NCM83.
View Article and Find Full Text PDFSmall
January 2025
Beijing Advanced Innovation Center for Intelligent Robots and Systems, School of Medical Technology, Beijing Institute of Technology, Beijing, 100081, P. R. China.
The propensity of zinc (Zn) to form irregular electrodeposits at liquid-solid interfaces emerges as a fundamental barrier to high-energy, rechargeable batteries that use zinc anodes. So far, tremendous efforts are devoted to tailoring interfaces, while atomic-scale reaction mechanisms and the related nanoscale strain at the electrochemical interface receive less attention. Here, the underlying atomic-scale reaction mechanisms and the associated nanoscale strain at the electrochemical alloy interface are investigate, using gold-zinc alloy protective layer as a model system.
View Article and Find Full Text PDFNanoscale Horiz
January 2025
Departmento de Fisica, Universidad Técnica Federico Santa María, Av. España 1680, Valparaíso, Chile.
Low-energy light ion beams are an essential resource in lithography for nanopatterning magnetic materials and interfaces due to their ability to modify the structure and properties of metamaterials. Here we create ferromagnetic/non-ferromagnetic heterostructures with a controlled layer thickness and nanometer-scale precision. For this, hydrogen ion (H) irradiation is used to reduce the antiferromagnetic nickel oxide (NiO) layer into ferromagnetic Ni with lower fluence than in the case of helium ion (He) irradiation.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming, 650093, P. R. China.
Designing and optimizing photocatalysts to maximize the use of sunlight and achieve fast charge transport remains a goal of photocatalysis technology. Herein, a full-spectrum-response BiOBr:Er@BiO core-shell S-scheme heterojunction is designed with [Bi─O] tetrahedral sharing using upconversion (UC) functionality, photothermal effects, and interfacial engineering. The UC function of Er and plasmon resonance effect of BiO greatly improves the utilization of sunlight.
View Article and Find Full Text PDFACS Appl Eng Mater
December 2024
Department of Chemistry and Biochemistry, Rowan University, Glassboro, New Jersey 08028, United States.
Carbon-based nanofibers are critical materials with broad applications in industries such as energy, filtration, and biomedical devices. Polyacrylonitrile (PAN) is a primary precursor for carbon nanofibers, but conventional electrospinning techniques typically operate at low production rates of 0.1-1 mL/h from a single spinneret, limiting scalability.
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