AI Article Synopsis
- The study examines infrared and Raman spectra of solutions in liquid argon and krypton featuring dimethyl ether and carbon dioxide isotopomers.
- The findings provide new information about specific CO(2) resonance frequencies within the CO(2)-ether complexes.
- Experimental data is complemented by advanced computational calculations to analyze force constants and dipole moments relevant to the observed resonances.
Article Abstract
Infrared and Raman spectra of solutions in liquid argon and krypton containing dimethyl ether or its fully deuterated isotopomer and (12)CO(2) or (13)CO(2) are investigated. The spectra lead to new data on the nu(1) (CO(2) )/2 nu(2) (CO(2) ) resonances appearing in the complex of CO(2) with the ether. The experimental data, and their interpretation, is supported by MP2/6-311++G(2d,2p) calculations of the cubic and quartic force constants and of the first and higher order dipole moment derivatives required for the modelling of the Fermi and Darling-Dennison resonances observed.
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| http://dx.doi.org/10.1002/cphc.200900414 | DOI Listing |
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