Two diamino-substituted lithiocarbanions in one molecule.

Chem Commun (Camb)

Lehrstuhl für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstrasse 15, 33615 Bielefeld, Germany.

Published: October 2009

tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a deprotonation intermediate has been isolated and structurally characterised.

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http://dx.doi.org/10.1039/b909561fDOI Listing

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Two diamino-substituted lithiocarbanions in one molecule.

Chem Commun (Camb)

October 2009

Lehrstuhl für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstrasse 15, 33615 Bielefeld, Germany.

tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a deprotonation intermediate has been isolated and structurally characterised.

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