tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a deprotonation intermediate has been isolated and structurally characterised.
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http://dx.doi.org/10.1039/b909561f | DOI Listing |
Chem Commun (Camb)
October 2009
Lehrstuhl für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstrasse 15, 33615 Bielefeld, Germany.
tert-Butyllithium deprotonates bis(3-methyl-1,3-diazacyclohex-1-yl)methane and its five-ring analogue regioselectively at both endocyclic NCH2N units; a deprotonation intermediate has been isolated and structurally characterised.
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