Oligosilylated group 4 titanocenes in the oxidation state +3.

Chem Commun (Camb)

Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, 8010 Graz, Austria.

Published: October 2009

Reactions of oligosilylanions with Cp2TiCl2 led to the formation of ate-complexes of silylated titanocenes, which form upon silylation of the intermediate K[Cp2TiCl2].18-crown-6.

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Source
http://dx.doi.org/10.1039/b910637eDOI Listing

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