Nonlinear kinetics of fast relaxation in solutions with short and lengthy micelles.

J Chem Phys

Department of Statistical Physics, St. Petersburg State University, Ulyanovskaya St. 1, Petrodvorets, St. Petersburg 198504, Russia.

Published: August 2009

An analytical treatment of the nonlinear kinetic equations for fast relaxation of coexisting short and lengthy micelles in surfactant solutions is presented. The kinetic equations can be written as a hierarchical set of differential equations for the moments of the aggregation number distribution function of micelles. It is shown that the moment equations can be successively integrated. As examples of the general approach, particular cases of short spherical micelles, lengthy cylindrical micelles, and coexisting short and lengthy micelles have been considered and compared to the results of linear kinetic theory of micellar fast relaxation. The results show that there is a strong interplay between coexisting short and lengthy micelles, even in the case when the total number of surfactant molecules aggregated in short micelles is small in comparison with that in lengthy micelles.

Download full-text PDF

Source
http://dx.doi.org/10.1063/1.3204699DOI Listing

Publication Analysis

Top Keywords

lengthy micelles
20
short lengthy
16
fast relaxation
12
coexisting short
12
micelles
9
kinetic equations
8
short
6
lengthy
6
nonlinear kinetics
4
kinetics fast
4

Similar Publications

Label-Free Plasmonic Detection of Untethered Nanometer-Sized Brownian Particles.

ACS Nano

October 2020

Huygens-Kamerlingh Onnes Laboratory, Leiden University, Postbus 9504, 2300 RA Leiden, The Netherlands.

Optical detection of individual nanometer-sized analytes, virus particles, and protein molecules holds great promise for understanding and control of biological samples and healthcare applications. As fluorescent labels impose restrictions on detection bandwidth and require lengthy and invasive processes, label-free optical techniques are highly desirable. Here, we introduce an optical technique capable of transforming gold nanorods commonly used as photostable labels into highly localized high-speed probes.

View Article and Find Full Text PDF

Tadpole toxicity prediction using chromatographic systems.

J Chromatogr A

October 2015

Departament de Química Analítica and Institut de Biomedicina (IBUB), Universitat de Barcelona, Martí i Franquès 1-11, 08028 Barcelona, Spain.

Toxicity has been emulated in tadpole species through chromatographic systems. The parameter studied to evaluate the non-specific toxicity of a compound is the narcosis concentration (Cnar), which is defined as the concentration needed for the immobilization of the organism. Because experimental investigation with animals is lengthy, costly, technically difficult, and ethically questionable, there is a great interest in developing surrogate physicochemical systems able to emulate biological systems to obtain the same information in a faster, more economic, and easier manner.

View Article and Find Full Text PDF

Amphiphilic block copolymers have emerged during last years as a fascinating substrate material to develop micellar nanocontainers able to solubilize, protect, transport, and release under external or internal stimuli different classes of cargos to diseased cells or tissues. However, this class of materials can also induce biologically relevant actions, which complement the therapeutic activity of their cargo molecules through their mutual interactions with biologically relevant entities (cellular membranes, proteins, organelles..

View Article and Find Full Text PDF

Nonlinear kinetics of fast relaxation in solutions with short and lengthy micelles.

J Chem Phys

August 2009

Department of Statistical Physics, St. Petersburg State University, Ulyanovskaya St. 1, Petrodvorets, St. Petersburg 198504, Russia.

An analytical treatment of the nonlinear kinetic equations for fast relaxation of coexisting short and lengthy micelles in surfactant solutions is presented. The kinetic equations can be written as a hierarchical set of differential equations for the moments of the aggregation number distribution function of micelles. It is shown that the moment equations can be successively integrated.

View Article and Find Full Text PDF

The influence of hydrophobic-block length on solubilisation capacity was examined for micelles of E(m)B(n) copolymers (E=oxyethylene, B=oxybutylene, subscripts denote number-average block lengths in repeat units) with B-block lengths in the range of 30-76 and with E-blocks of sufficient length to ensure the formation of spherical micelles. Griseofulvin was used as a model poorly-water-soluble drug known to be almost exclusively solubilised in the micellar core. Combination of solubilisation data with those of a previous study has shown that the amount of drug solubilised per gram of hydrophobe is essentially independent of B-block length when this exceeds about 15 B units, suggesting that core size is not a major influence on solubilisation.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!