A luminescent homochiral 3D metal-organic framework, [Cd(dtba)(bpp)](3n) () (H(2)dtba = 2,2'-dithiobisbenzoic acid, bpp = 1,3-bis(4-pyridyl)propane), with an unprecedented threefold interpenetrating uniform network (8(6)), constructed from [Cd(dtba)](n) single helices and [Cd(bpp)](n) double-stranded helices, has been synthesized via hydrothermal reaction.
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