AI Article Synopsis
- The text discusses a highly efficient microwave synthesis method for creating the compound [RuCp(naphthalene)][PF(6)], which serves as a precursor for another compound [RuCp(CH(3)CN)(3)][PF(6)].
- It highlights the use of Pd-catalysed asymmetric hydrogenolysis, a chemical reaction that achieves high levels of selectivity for specific molecular orientations, leading to the formation of planar chiral ruthenium complexes.
- The reaction employs a bulky chiral phosphoramidite ligand, which plays a crucial role in achieving the desired enantioselectivity in the final product.
Article Abstract
Key elements in this communication are a very efficient microwave synthesis of [RuCp(naphthalene)][PF(6)], the precursor of [RuCp(CH(3)CN)(3)][PF(6)], and a Pd-catalysed asymmetric hydrogenolysis to afford planar chiral ruthenium complexes with high levels of enantioselectivity using a bulky chiral phosphoramidite ligand.
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| http://dx.doi.org/10.1039/b910977c | DOI Listing |
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