A controlled simulation experiment was performed to assess whether dislodgeable arsenic can be tracked onto carpets via foot traffic from chromated copper arsenate (CCA) pressure-treated decks. The pilot simulation study demonstrated that it is possible to track arsenic from CCA-decks onto carpets under the test conditions evaluated. A total of nine CCA-decks and two non-CCA-treated control surfaces were tested under wet and dry conditions. Five participants walked in a controlled manner (60 cycles, 11 steps per cycle) across decks and then walked over various lanes of carpet to simulate the tracking of arsenic indoors on the bottoms of shoes under heavy foot traffic conditions. To determine if arsenic was transferred from the CCA-treated wood to the carpet via shoes, laboratory analysis was performed on three different types of samples: (1) wipe samples of dislodgeable arsenic from a 46 cm(2) area of carpet, (2) dust samples obtained from vacuuming a 7442 cm(2) area of carpet, and (3) extractions of 13 cm(2) carpet samples. Wipe samples were also taken directly from the deck lumber. Following digestion and extraction, the amount of arsenic in each sample was measured using Graphite Furnace Atomic Absorption Spectrometry. The mean arsenic concentration measured on the carpets was 2.52 microg/(100 cm(2)) and 2.05 microg/(100 cm(2)) with wipes for the dry and wet conditions, respectively, 4.69 microg/(100 cm(2)) and 0.68 microg/(100 cm(2)) with vacuumed dust for the dry and wet conditions, respectively, and 15.56 microg/(100 cm(2)) and 12.31 microg/(100 cm(2)) with carpet extractions for the dry and wet conditions, respectively. The mean arsenic concentration measured on the decks was 22.2 microg/(100 cm(2)) with wipes. Further research is needed to determine if indoor exposure to arsenic due to track-in from outdoor decks via foot traffic is significant compared to exposures from other sources.
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http://dx.doi.org/10.1016/j.scitotenv.2009.07.022 | DOI Listing |
Talanta
April 2010
Forensic Science Programme, Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand.
Evaluation of the risk posed by contaminants present during and after decontamination of clandestine methamphetamine laboratories requires a connection between the levels of contaminants measured and those actually present at the scene. The recoveries of pseudoephedrine and methamphetamine from glass, stainless steel, and a range of impermeable surfaces likely to be found in a clandestine laboratory were examined, using GC-MS of derivatized samples as the analytical method. When surfaces had been cleaned prior to drug deposition, wiping with water-dampened filter paper can recover 60-80% of pseudoephedrine immediately after deposition, and at least 50% of the pseudoephedrine still present on a surface after 2 days when deposited at a surface concentration of 2.
View Article and Find Full Text PDFToxicol Ind Health
February 2010
Department of Environmental and Occupational Health, University of Montreal, Montreal, Quebec, Canada.
Beryllium (Be) is used in several forms: pure metal, beryllium oxide, and as an alloy with copper, aluminum, or nickel. Beryllium oxide, beryllium metal, and beryllium alloys are the main forms present in the workplace, with inhalation being the primary route of exposure. Cases of workers with sensitization or chronic beryllium disease challenge the scientific community for a better understanding of Be toxicity.
View Article and Find Full Text PDFSci Total Environ
November 2009
University of North Carolina at Asheville, Asheville, NC 28804, USA.
A controlled simulation experiment was performed to assess whether dislodgeable arsenic can be tracked onto carpets via foot traffic from chromated copper arsenate (CCA) pressure-treated decks. The pilot simulation study demonstrated that it is possible to track arsenic from CCA-decks onto carpets under the test conditions evaluated. A total of nine CCA-decks and two non-CCA-treated control surfaces were tested under wet and dry conditions.
View Article and Find Full Text PDFAnn Occup Hyg
October 2009
Department of Environmental and Occupational Health, Faculty of Medicine, Université de Montréal, Pavillon Marguerite-d'Youville 2375, Chemin de la Côte-Ste-Catherine, Montréal, Québec H3T 1A8, Canada.
The objective of the present work was to estimate the efficiency of moistened wipes in removing beryllium with different solutions including Citranox, Alconox, NaCl 5%, Resolve, and Ledizolv on various types of surfaces such as unpainted metal, wood frames, painted metal, concrete, painted concrete, and Plexiglas from three different occupational settings. Of the three plants that were investigated, only surfaces in the aluminium smelter were decontaminated down to the clearance reference level of 0.2 microg 100 cm(-2), with all the solvents used.
View Article and Find Full Text PDFJ Expo Sci Environ Epidemiol
May 2009
Division of Respiratory Disease Studies, Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health, Morgantown, West Virginia 26505-2888, USA.
Cobalt, chromium and nickel are among the most commonly encountered contact allergens in the workplace, all used in the production of cemented tungsten carbides (CTC). Exposures to these metal-containing dusts are frequently associated with skin sensitization and/or development of occupational asthma. The objectives of this study were to assess the levels of cobalt, chromium and nickel on work surfaces and on workers' skin in three CTC production facilities.
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