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A ring-opening metathesis polymerization route to alkaline anion exchange membranes: development of hydroxide-conducting thin films from an ammonium-functionalized monomer. | LitMetric
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A ring-opening metathesis polymerization route to alkaline anion exchange membranes: development of hydroxide-conducting thin films from an ammonium-functionalized monomer.

Timothy J Clark Nicholas J Robertson Henry A Kostalik Emil B Lobkovsky Paul F Mutolo Héctor D Abruña Geoffrey W Coates

J Am Chem Soc

Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York, 14853-1301, USA.

Published: September 2009

We report the development of a facile ring-opening olefin metathesis route to alkaline anion exchange membranes via the copolymerization of a tetraalkylammonium-functionalized norbornene with dicyclopentadiene. The thin films generated are mechanically strong and exhibit high hydroxide conductivities and exceptional methanol tolerance.

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http://dx.doi.org/10.1021/ja905242rDOI Listing

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