A review of past and present published works examining the interaction of polymeric dispersants with titania pigment particles is presented. Titania is the most important white pigments currently used in the world and its suspension properties are very important for consumer industries such as paints, papermaking and plastics; if aggregates are present, the end-use properties including gloss, opacity and storage stability will be highly affected. As polymeric dispersants are generally used to disperse titania pigment particles, it is very important to understand the interactions between the pigment particles and polymeric dispersants of varying functionality. Although, in principle, the adsorption of polymers onto titania pigment and influences on pigment dispersion and stabilisation are fairly known, it is nevertheless hardly possible to forecast the behaviour of a given polymeric dispersant in advance, unless to have a broad knowledge of the interaction occurring between pigment and dispersants and effect of dispersant structure upon adsorption. While only titania pigment is discussed, the issues raised may also apply to other mineral oxides such as alumina or zirconia.
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http://dx.doi.org/10.1016/j.cis.2009.07.004 | DOI Listing |
Stud Health Technol Inform
November 2024
School of Civil Engineering, University of Leeds, UK.
Chemosphere
December 2024
Department of Chemistry and Biochemistry, University of Texas at El Paso, Texas, USA; Environmental Science and Engineering Program, University of Texas at El Paso, Texas, USA.
Life (Basel)
November 2024
Department of Biological, Geological and Environmental Sciences, University of Catania, 95124 Catania, Italy.
Nowadays, developing countries have seen a reduction in male reproductive parameters, and it has been linked to the exposure of endocrine disrupting chemicals (EDCs), which are able to mimic or disrupt steroid hormone actions. Also, nanoparticles have shown effects on the male reproductive system, in particular the use of TiO-NPs in drugs, cosmetics, and food as pigment additives, and, thanks to their small size (1-100 nm), provide themselves the opportunity to be internalized by the body and pass the blood-testis barrier (BTB). Therefore, TiO-NPs can act on spermatogenesis and spermatozoa.
View Article and Find Full Text PDFNanoscale
December 2024
Materials Architecturing Research Centre, Korea Institute of Science and Technology, 5 Hwarang-ro 14-gil, Seoul 02792, Republic of Korea.
This study addresses the inherent photocatalytic activity of pure titanium dioxide (TiO), which limits its application as an industrial pigment. To mitigate this issue, a core-shell structure was employed, where TiO cores were encapsulated within SiO shells. Perhydropolysilazane (PHPS) was introduced as a superior SiO precursor over tetraethylorthosilicate (TEOS), resulting in thinner and more uniform SiO shells.
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