The coordination of AlCl(3) by the complex [{MeAl(2-py)(3)}Li.thf] () gives the unusual product [{MeAl(2-py)(3)}(2)Al](+)[{MeAl(2-py)(3)}Li](2)(mu-Cl)(-) (), in which the [MeAl(2-py)(3)](-) aluminate anion of acts cooperatively in the coordination of an Al(3+) cation and Cl(-) anion.

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http://dx.doi.org/10.1039/b909933fDOI Listing

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