MIL-101, a mesoporous chromium terephthalate metal organic framework, was found to be an efficient heterogeneous catalyst for selective oxidation of tetralin to 1-tetralone using tert-butyl hydroperoxide or acylperoxy radicals generated in situ from trimethylacetaldehyde and O(2) as an oxidant.
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http://dx.doi.org/10.1039/b902699a | DOI Listing |
Elife
January 2025
Department of Social and Applied Nutrition, Federal University of Rio de Janeiro, Rio de Janeiro, Brazil.
The role of circulating metabolites on child development is understudied. We investigated associations between children's serum metabolome and early childhood development (ECD). Untargeted metabolomics was performed on serum samples of 5,004 children aged 6-59 months, a subset of participants from the Brazilian National Survey on Child Nutrition (ENANI-2019).
View Article and Find Full Text PDFOrg Lett
January 2025
Jiangsu Key Laboratory of Pesticide Science and Department of Chemistry, College of Sciences, Nanjing Agricultural University, Nanjing, 210095, P. R. China.
Radical-initiated functionalization of bicyclo[1.1.0]butanes (BCBs) is a straightforward approach to accessing diverse cyclobutane derivatives.
View Article and Find Full Text PDFSmall Methods
January 2025
State Key Laboratory of Green Pesticide, Key Laboratory of Green Pesticide & Agricultural Bioengineering, Ministry of Education, State-Local Joint Laboratory for Comprehensive Utilization of Biomass, Center for R&D of Fine Chemicals, Guizhou University, Guiyang, Guizhou, 550025, China.
Photocatalytic transfer hydrogenation of biomass-derived aldehydes to alcohols often results in unwanted coupling co-products. Herein, an ultraselective hydrogen transfer system enabled by in situ oxidative C─C bond cleavage over a Janus single-atom palladium on titanium dioxide (0.5Pd/TiO) photocatalyst is presented.
View Article and Find Full Text PDFiScience
January 2025
Electrical Engineering College, Guizhou University, Guiyang 550025, China.
Analyzing the uniformity of ammonia distribution at the inlet of selective catalytic reduction reactors is crucial for enhancing denitrification efficiency. To minimize ammonia slip while ensuring effective denitrification, this study examines ammonia flow characteristics in the SCR system under various zoning schemes. In scheme I, zones A1, A2, A3, and A4 predominantly influence the left, center, center-right, and far-right regions of the reactor inlet.
View Article and Find Full Text PDFData Brief
February 2025
CREA - Council for Agricultural Research and Economics, Research Centre for Agriculture and Environment, I-40128 Bologna, Italy.
Farming practices such as soil tillage, organic/mineral fertilization, irrigation, crop selection and residues management influence multiple ecosystem services provided by agricultural systems. These practices exhibit complex, non-linear interrelationships that affect crop productivity, water quality, and non-carbon dioxide greenhouse gases (GHG) emissions, possibly offsetting their benefits regarding soil organic carbon (SOC) sequestration. Current methodologies from the Intergovernmental Panel on Climate Change (IPCC) for assessing the impacts of alternative farming practices on GHG emissions rely on global or country-specific coefficients.
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