Deuterium-labelled compounds were prepared by (transfer) deuterogenation of unsaturated compounds using H(2) or HCO(2)H in acidic D(2)O as deuterium source with almost quantitative yields and high deuterium contents under mild reaction conditions via heterolytic cleavage of H(2) (or decomposition of HCO(2)H) and rapid H(+)/D(+) exchange using iridium catalysts with 4,4'-dihydroxy-2,2'-bipyridine.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/b908764h | DOI Listing |
Publication Analysis
Top Keywords
transfer deuterogenation
8
d2o deuterium
8
deuterium source
8
catalytic transfer
4
deuterogenation d2o
4
source hco2h
4
hco2h electron
4
electron sources
4
sources deuterium-labelled
4
deuterium-labelled compounds
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!