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Cr-Doped Nanocrystalline TiO-CrO Nanocomposites with p-p Heterojunction as a Stable Gas-Sensitive Material.
Int J Mol Sci
January 2025
Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia.
Nanocrystalline TiO is a perspective semiconductor gas-sensing material due to its long-term stability of performance, but it is limited in application because of high electrical resistance. In this paper, a gas-sensing nanocomposite material with p-p heterojunction is introduced based on p-conducting Cr-doped TiO in combination with p-conducting CrO. Materials were synthesized via a single-step flame spray pyrolysis (FSP) technique and comprehensively studied by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) specific surface area analysis, transition electron microscopy (TEM), energy dispersive X-ray (EDX) spectroscopy, X-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance (EPR), and Raman spectroscopy.
View Article and Find Full Text PDFStimuli-Chromic Oxazolidine Latex Nanoparticles for Dual-Responsive pH-Sensors and Rewritable Halochromic Papers: A Physicochemical Study on Colorimetric and Fluorimetric Signals.
ACS Appl Mater Interfaces
January 2025
Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731, Iran.
Oxazolidine is a new category of stimuli-chromic compounds that has unique intelligent behaviors such as halochromism, hydrochromism, solvatochromism, and ionochromism, all of which have potential applications for designing and constructing chemosensors by using functionalized-polymer nanocarriers. Here, the poly(MMA--HEMA) based nanoparticles were synthesized by emulsion copolymerizing methyl methacrylate (MMA) and 2-hydroxyethyl methacrylate (HEMA) in different copolymer compositions. The poly(MMA--HEMA) based nanoparticles were modified physically with tertiary amine-functionalized oxazolidine (as an intelligent pH-responsive organic dye) to prepare halochromic latex nanoparticles.
View Article and Find Full Text PDFChromic Electrospun Polymer Nanofibers: Preparation, Applications, and the Future.
ACS Appl Mater Interfaces
January 2025
Supramolecular Chemistry Group, Centre of Macromolecular Chemistry (CMaC), Department of Organic and Macromolecular Chemistry, Faculty of Sciences, Ghent University, Krijgslaan 281, S4-bis, B-9000 Ghent, Belgium.
Physical understanding and determination of different analytes without the need for advanced and additional equipment are highly important, which can be achieved by using stimuli-induced chromic materials. Physical and chemical incorporation of responsive chromophores into different polymers results in the fabrication of chromic polymers. Chromic electrospun nanofibers are prepared using the electrospinning technique, and their stimuli-responsivity is improved due to their high surface-to-volume ratio.
View Article and Find Full Text PDFAdvanced Design for Stimuli-Reversible Chromic Wearables With Customizable Functionalities.
Adv Mater
December 2024
Nanotechnology Center, School of Fashion and Textiles, The Hong Kong Polytechnic University Hung Hom, Kowloon, Hong Kong, 999077, China.
Smart wearable devices with dynamically reversible color displays are crucial for the next generation of smart textiles, and promising for bio-robots, adaptive camouflage, and visual health monitoring. The rapid advancement of technology brings out different categories that feature fundamentally different color-reversing mechanisms, including thermochromic, mechanochromic, electrochromic, and photochromic smart wearables. Although some reviews have showcased relevant developments from unique perspectives, reviews focusing on the advanced design of flexible chromic wearable devices within each category have not been reported.
View Article and Find Full Text PDFCholesteric Liquid Crystal Network Composite Film with Structure, Dual-Band Responsive Luminescent Color for Multiple Anti-Counterfeiting and Information Encryption.
ACS Appl Mater Interfaces
December 2024
Department of Applied Physics, Hebei University of Technology, Tianjin 300401, PR China.
Anti-counterfeiting technology plays an indispensable role in the high-tech field and various critical application areas. However, traditional anti-counterfeiting approaches currently in widespread use are too simplistic and easily replicated or forged, while advanced technologies with multiple anti-counterfeiting functions remain in the developmental stage. This study presents a novel multiple anti-counterfeiting technique.
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