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Enzymatic Hydrolysis Systems Enhance the Efficiency and Biological Properties of Hydrolysates from Frozen Fish Processing Co-Products.
Mar Drugs
December 2024
Division of Aquaculture, Upgrading and Bioprospection, Portuguese Institute for the Sea and Atmosphere (IPMA, I.P.), Av. Doutor Alfredo Magalhães Ramalho 6, 1495-165 Algés, Portugal.
Co-products from the frozen fish processing industry often lead to financial losses. Therefore, it is essential to transform these co-products into profitable goods. This study explores the production of fish protein hydrolysates (FPH) from three co-products: the heads and bones of black scabbardfish (), the carcasses of gilthead seabream (), and the trimmings of Nile perch ().
View Article and Find Full Text PDFDirect Observation of Structural Phase Transformations during Phosphorene Formation on Cu(111).
ACS Nano
January 2025
Institute of Physical Engineering, Brno University of Technology, Technická 2, 616 69 Brno, Czech Republic.
Blue phosphorene, a two-dimensional, hexagonal-structured, semiconducting phosphorus, has gained attention as it is considered easier to synthesize on metal surfaces than its allotrope, black phosphorene. Recent studies report different structures of phosphorene, for example, on Cu(111), but the underlying mechanisms of their formation are not known. Here, using a combination of in situ ultrahigh vacuum low-energy electron microscopy and in vacuo scanning tunneling microscopy, we determine the time evolution of the surface structure and morphology during the deposition of phosphorus on single-crystalline Cu(111).
View Article and Find Full Text PDFReactivity of a Stable and Highly Electron-Rich (η-Diborabenzene)nickel(0) Synthon.
Inorg Chem
January 2025
Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg 97074, Germany.
The reaction of the diborabenzene (DBB) nickel(0) pogo-stick complex [(η-DBB)Ni(CO)] () with a large excess of [Ni(CO)] yields the dark green, unstable dinickel(0) complex [(η-DBB)Ni(μ-CO)Ni(CO)] (), which loses one CO ligand to yield the purple, bimetallic Ni half-sandwich complex [(η-DBB)Ni(μ-CO)(η-CO)] (). The addition of the chromium aminoborylene complex [(OC)Cr{BN(TMS)}] (TMS = trimethylsilyl) to does not result in the expected borylene transfer but in the formation of the black Ni-Cr complex [(η-DBB)Ni(μ-CO)Cr(CO)] (), alongside the dimeric iminoborane [(TMS)BN(TMS)] (), which results from the rearrangement of the released BN(TMS) aminoborylene moiety. Furthermore, the oxidative addition of methyl triflate (MeOTf) to leaves the (η-DBB)Ni moiety intact and provides the ionic Ni half-sandwich complex [(η-DBB)NiMe(CO)]OTf (), while reaction with pentaphenylborole (PPB) yields the unique, dark-blue, unsymmetrical sandwich complex [(η-DBB)Ni(μ-CO)(η-PPB)] ().
View Article and Find Full Text PDFHuman epidermal growth factor receptor 2 (HER2, also known as ERBB2) signaling promotes cell growth and differentiation, and is overexpressed in several tumor types, including breast, gastric and colorectal cancer. HER2-targeted therapies have shown clinical activity against these tumor types, resulting in regulatory approvals. However, the efficacy of HER2 therapies in tumors with HER2 mutations has not been widely investigated.
View Article and Find Full Text PDFEffectiveness of workplace health promotion programs for industrial workers: a systematic review.
BMC Public Health
January 2025
Department of Movement and Training Science, University of Wuppertal, Wuppertal, Germany.
Background: Workplace health promotion is essential for individual and organisational well-being and disease prevention, also in industrial workers. As the transfer of the evidence on the effectiveness of such programs into practice is limited due to scattered effects, the need for a consolidation of the available studies is given. The purpose of this systematic review was to synthesise the evidence on the effectiveness of workplace health promotion programs for industrial workers.
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