A convective directed-assembly process on a flat substrate that does not require motion and is followed by a dry-transfer process of nanoparticles is presented. The convective assembly process was achieved using Au nanoparticles on hydrophobic/hydrophilic-surface-patterned Si substrates as functions of temperature, gap height, and particle size. An investigation of the particle assembly mechanism showed that the effects of temperature, gap height, and particle size were responsible for controlling the evaporation time, the evaporation length, and the assembly speed, respectively. To ensure conformal contact during the dry-transfer process, chemically patterned hybrid templates with elastic and flexible properties were fabricated and used. The hybrid templates provided conformal contact with a target silicon substrate coated with MPTMS (3-mercaptopropyltrimethoxysilane) and successfully transferred Au particles to the target substrates.
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http://dx.doi.org/10.1021/la901496s | DOI Listing |
Angew Chem Int Ed Engl
December 2024
MOE Key Laboratory of Cluster Science, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 102488, P. R. China.
The directional assembly of porous organic molecules into long-range ordered architectures, featuring controlled hierarchical porosity and oriented pore channels with defined spatial arrangements, is a fundamental challenge in chemistry and materials science. Herein, using porous organic cages as starting units, we present a cooperative multiscale-assembly strategy enabling the simultaneous alignment of pore channels and directional hierarchical growth in a single step. At the microscopic level, we employed double solvents to manipulate the intermolecular packing of microporous tetrahedral [4+6] imine cages (CC1 and CC3), resulting in pore channel orientation.
View Article and Find Full Text PDFMater Horiz
December 2024
North Carolina State University, Department of Materials Science & Engineering, Raleigh, NC 27695, USA.
Soft Matter
November 2024
Department of Chemical Engineering, University of California, Santa Barbara, Santa Barbara, CA 93106, USA.
Active matter systems are strongly driven to assume non-equilibrium distributions owing to their self-propulsion, , flocking and clustering. Controlling the active matter systems' spatiotemporal distributions offers exciting applications such as directed assembly, programmable materials, and microfluidic actuation. However, these applications involve environments with coupled dynamics and complex tasks, making intuitive control strategies insufficient.
View Article and Find Full Text PDFNanoscale
September 2024
Center for Photonic Science and Engineering, Skolkovo Institute of Science and Technology, 30 Bld. 1 Bolshoy Boulevard, 121205, Russia.
Microsyst Nanoeng
September 2024
Photonics Research Center, School of Optoelectronic Engineering, Guilin University of Electronic Technology, Guilin, 541004, China.
Field-controlled micromanipulation represents a pivotal technique for handling microparticles, yet conventional methods often risk physical damage to targets. Here, we discovered a completely new mechanism for true noncontact manipulation through photothermal effects, called thermal-optical tweezers. We employ a laser self-assembly photothermal waveguide (PTW) for dynamic microparticle manipulation.
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