Efficient and mild reaction conditions were developed for the catalytic carbonylation of fluorinated epoxides to their corresponding β-lactones. Six new lactones with fluorinated side chains were prepared in high isolated yields. These lactones were polymerized to form a series of new poly(β-hydroxyalkanoate)s with fluorinated side chains, and their properties were examined with respect to their hydrocarbon analogs. Finally, copolymerizations were performed with fluorinated lactones and β-butyrolactone, which resulted in tapered copolymers rather than the expected random copolymers.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2583445 | PMC |
| http://dx.doi.org/10.1016/j.tet.2008.03.108 | DOI Listing |
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