CdCu(3)(OH)(6)(NO(3))(2): An S = (1)/(2) Kagomé antiferromagnet.

Inorg Chem

Department of Chemistry, Massachusetts Institute of Technology,77 Massachusetts Avenue, Cambridge, Massachusetts 02139-4307, USA.

Published: August 2009

The cadmium copper hydroxide nitrate, CdCu(3)(OH)(6)(NO(3))(2).0.5H(2)O, is furnished from oxygenated suspensions of Cu(2)O in aqueous Cd(NO(3))(2). The compound possesses the kagome structural motif and shows no evidence of magnetic ordering to temperatures as low as 5 K, despite exhibiting a Curie-Weiss temperature of Theta = -114 +/- 27 K, thus giving a spin frustration parameter, f = 22.8.

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http://dx.doi.org/10.1021/ic900665jDOI Listing

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