A novel supporting material containing benzenesulfonic acid (BSA) groups and ordered mesoporous carbons (OMCs) was first prepared by in situ radical polymerization of 4-styrenesulfonate and isoamyl nitrite under ambient conditions. Then, Pd nanoparticles were deposited on as-produced OMCs (f-OMCs) by the NaBH(4) reduction method. The structure and nature of the resulting composites were characterized by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and nitrogen adsorption-desorption. The results show that BSA groups are created and the texture and surface chemistry are altered, whereas the ordered porous structure is maintained. The electrocatalytic properties of the Pd/f-OMCs catalysts for formic acid oxidation (HCOOH) have been investigated by cyclic voltammetry and chronoamperometry methods, and excellent electrocatalytic activity can be observed.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.jcis.2009.05.030 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Efficient adsorptive removal of Congo Red dye using activated carbon derived from Spathodea campanulata flowers.
Sci Rep
January 2025
Department of Chemical Engineering, Manipal Institute of Technology, Manipal Academy of Higher Education, Manipal, Karnataka, 576104, India.
This report investigates the preparation, characterization, and application of activated carbon derived from Spathodea campanulata flowers (SCAC) to remove Congo Red (CR) dye from aqueous streams. SCAC was synthesized using orthophosphoric acid activation which yielded a mesoporous material with a specific surface area of (986.41 m/g), significantly exceeding values reported for flower-derived activated carbons in the available literature.
View Article and Find Full Text PDFSynergetic effects of nano-boehmite and Y nano-zeolite on catalytic cracking of residue oil.
Sci Rep
January 2025
Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar, Iran.
Boehmite nanoparticles and NaY nanozeolite were synthesized by co-precipitation and hydrothermal methods, respectively, and characterized by XRD, FT-IR, TG-DTA, BET, and SEM techniques. XRD and BET analyses demonstrated the formation of boehmite nanoparticles with a surface area of 350 m/g and high crystallinity NaY nanozeolite with a surface area of 957 m/g. In order to evaluate the effect of the content of the mesoporous boehmite nanoparticles on the catalytic performance of the Residue Fluid Catalytic Cracking (RFCC) catalyst, alumina active matrix-based and silica inactive matrix-based catalysts were prepared.
View Article and Find Full Text PDFInterfacial adsorption behavior of amine-functionalized MCM-41 for Mo(VI) capture from aqueous solution.
Environ Res
January 2025
School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China; Zhongyuan Critical Metals Laboratory, Zhengzhou University, Zhengzhou 450001, China; The Key Lab of Critical Metals Minerals Supernormal Enrichment and Extraction, Ministry of Education, Zhengzhou 450001, China.
Given the environmental and ecological risks posed by wastewater bearing Mo, the characteristics and microscopic interactions of existing silica-based adsorbents have not been thoroughly investigated, highlighting the need to enhance the porosity and chemical interactions of these materials. Considering the effectiveness of amino groups in binding metal oxyanions, this study investigates the adsorption performance and mechanism of amino-functionalized MCM-41 for Mo(VI), with the goal of efficiently remediating Mo-contaminated wastewater. MCM-41 modified by amino group retains its original structure and mesoporous characteristics while featuring a positively charged surface and chemically bonded amino groups.
View Article and Find Full Text PDFImpact of composition and surfactant-templating on mesoporous bioactive glasses structural evolution, bioactivity, and drug delivery property.
J Biomater Appl
January 2025
Biomedical Engineering Graduate Program, Toronto Metropolitan University, Toronto, ON, Canada.
This study explores mesoporous bioactive glasses (MBGs) that show promise as advanced therapeutic delivery platforms owing to their tailorable porous properties enabling enhanced drug loading capacity and biomimetic chemistry for localized, sustained release. This work systematically investigates the complex relationship between MBG composition and surfactant templating on structural evolution, bioactive response, resultant drug loading efficiency and release. A total of 12 samples of sol-gel-derived MBG were synthesized using cationic and non-ionic structure-directing agents (cetyltrimethylammonium bromide, Pluronic F127 and P123) while modulating the SiO/CaO content, generating MBG with surface areas of 60-695 m/g.
View Article and Find Full Text PDFAdvanced Analysis of Clay Microporosity Using High-Resolution N-Ar Adsorption Isotherms Coupled with the Derivative Isotherm Summation Method.
Molecules
December 2024
IMT Atlantique, GEPEA, UMR CNRS 6144, F-44307 Nantes, France.
The textural properties of synthetic and natural clays in the sodium form and exchanged with tetramethylammonium cations (TMA) were characterized using N and Ar physisorption isotherms at cryogenic temperatures. Specific surface areas and micro/mesoporous volumes were determined using the BET and the models. The analysis requires the use of reference isotherms measured at the same temperature on the surface of non-porous materials with an identical chemical composition.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!