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A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates. | LitMetric
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A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates.

Derek C Vrieze Garrett S Hoge Perrine Z Hoerter Jared T Van Haitsma Brian M Samas

Org Lett

Pfizer Global Research and Development, 2800 Plymouth Road, Ann Arbor, Michigan 48105, USA.

Published: July 2009

A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed.

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 Source
http://dx.doi.org/10.1021/ol901031bDOI Listing

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