Wet extraction of heavy metals and chloride from MSWI and straw combustion fly ashes.

Waste Manag

Hamburg University of Technology, Institute of Environmental Technology and Energy Economics, Eissendorfer Street 40, D-21073 Hamburg, Germany.

Published: September 2009

Fly ash residues from combustion often do not meet the criteria neither for reuse as construction materials nor landfilling as non-hazardous waste, mainly because of the high concentration of heavy metals and chlorides. This work aimed to technically evaluate an innovative wet treatment process for the extraction of chloride (Cl(-)), cadmium (Cd), copper (Cu), lead (Pb) and zinc (Zn) from fly ashes from a municipal solid waste incineration (MSWI) plant and from a straw combustion (SC) facility. Factors investigated were liquid/solid (L/S) ratio, full carbonation (CO(2) treatment), influence of pH and leaching time, using a two-level full factorial design. The most significant factor for all responses was low pH, followed by L/S ratio. Multiple linear regression models describing the variation in extraction data had R(2) values ranging from 58% to 98%. An optimization of the element extraction models was performed and a set of treatment conditions is suggested.

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http://dx.doi.org/10.1016/j.wasman.2009.04.013DOI Listing

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