We report an experiment that directly measures the Laplace transform of the recurrence probability in one dimension using electromagnetically induced transparency (EIT) of coherent atoms diffusing in a vapor cell filled with buffer gas. We find a regime where the limiting form of the complex EIT spectrum is universal and only depends on the effective dimensionality in which the random recurrence takes place. In an effective one-dimensional diffusion setting, the measured spectrum exhibits power-law dependence over two decades in the frequency domain with a critical exponent of 0.56 close to the expected value 0.5.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1103/PhysRevLett.102.150602 | DOI Listing |
J Phys Chem A
January 2025
Department of Chemistry and Chemical Biology, Center for Computational Chemistry, University of New Mexico, Albuquerque, New Mexico 87131, United States.
The kinetics of electronically inelastic quenching of O(Δ) and O(Σ) by collisions with O(P) have been investigated using mixed quantum-classical trajectories governed by adiabatic potential energy surfaces and state couplings generated from a recently developed diabatic potential energy matrix (DPEM) for the 14 lowest-energy A' states of O. Using the coherent switching with decay of mixing (CSDM) method, dynamics calculations were performed both with 14 coupled electronic states and with 8 coupled electronical states, and similar results were obtained. The calculated thermal quenching rate coefficients are generally small, but they increase with temperature.
View Article and Find Full Text PDFThe macroscopic mechanism of light traveling based on the general Snell's laws records the interactions between the gradient phases of meta-surfaces and the involved fields, but it can hardly adequately account for the detailed contributions of meta-atoms to the behaviors of light. Here, we demonstrate the light-microscopic observation of the interference from meta-atoms to characterize the meta-surface with the inhomogeneous spatial distribution of surface susceptibility. The meta-surface will generate multi-order diffractions with a main propagating channel and several other weaker channels, and the light emitted by the meta-atoms will also coherently cancel out the original incidence.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Science Institute and Faculty of Physical Sciences, University of Iceland, Reykjavík, Iceland.
Understanding the ultrafast vibrational relaxation following photoexcitation of molecules in a condensed phase is essential to predict the outcome and improve the efficiency of photoinduced molecular processes. Here, the vibrational decoherence and energy relaxation of a binuclear complex, [Pt2(P2O5H2)4]4- (PtPOP), upon electronic excitation in liquid water and acetonitrile are investigated through direct adiabatic dynamics simulations. A quantum mechanics/molecular mechanics (QM/MM) scheme is used where the excited state of the complex is modeled with orbital-optimized density functional calculations while solvent molecules are described using potential energy functions.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
This study investigates the motion of an electron in a Coulomb potential driven by an intense linearly polarized XUV laser pulse analyzed using Gordon-Volkov wave functions. The wave function is decomposed into spherical partial waves to model the scattered electron wave packet after the recollision with a proton. This interaction triggers high harmonic generation, producing coherent X-ray pulses with frequencies that are integer multiples of the XUV field.
View Article and Find Full Text PDFNat Phys
November 2024
Laboratory of Physical Chemistry, ETH Zürich, Zurich, Switzerland.
A dynamical rearrangement in the electronic structure of a molecule can be driven by different phenomena, including nuclear motion, electronic coherence or electron correlation. Recording such electronic dynamics and identifying its fate in an aqueous solution has remained a challenge. Here, we reveal the electronic dynamics induced by electronic relaxation through conical intersections in both isolated and solvated pyrazine molecules using X-ray spectroscopy.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!