Two dimensional magnetic and optical spectra contain information about structure and dynamics inaccessible to the linear spectroscopist. Recently, phase cycling techniques in optical spectroscopy have extended the capabilities of two-dimensional electronic spectroscopy. Here, we present a method to generate collinear pump/probe pulses at high update rates for two-dimensional electronic spectroscopy. Both fluorescence mode and transmission mode photon echo data from rubidium vapor is presented.

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http://dx.doi.org/10.1364/opex.13.003697DOI Listing

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