A 3D porous hetero-metal compound, which is constructed from the heptanuclear zinc clusters has two types of helical channels, and shows hydrogen adsorption capacity when loaded at 77 K under 0.8 MPa.
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January 2021
School of Physics and Information Technology, Shaanxi Normal University, Xi'an, 710062, China.
The energy conversion efficiency of water electrolysis is determined by the activity of selected catalysts. Ideal catalysts should possess not only porous architecture for high-density assembly of active sites but also a subtle electronic configuration for the optimized activity at each site. In this context, the development of stable porous hosting materials that allow the incorporation of various metal elements is highly desirable for both experimental optimization and theoretical comparison/prediction.
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December 2017
Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India.
Herein, for the first time, we applied the metal-metal-bond-energy factor to the evolution of a porous Se-Te alloy. The porous Se-Te material has been prepared from the constituents' elemental states, through only a heating-cooling process in silicone oil without the use of any reagent, surfactant, or capping agent. Surprisingly, the reaction occurred at a much lower temperature (240 °C) than the mp (450 °C) of Te.
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June 2009
Department of Chemistry, Nankai University, Tianjin 300071, P. R. China.
A 3D porous hetero-metal compound, which is constructed from the heptanuclear zinc clusters has two types of helical channels, and shows hydrogen adsorption capacity when loaded at 77 K under 0.8 MPa.
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