AI Article Synopsis
- The study explores the use of iminium and enamine catalysts working together to achieve various effective asymmetric transformations in organic chemistry.
- This includes processes like 1,2-hydroamination, hydro-oxidation, and amino-oxidation of olefins.
- Additionally, an enantioselective organocascade catalysis was successfully utilized in the creation of a complex natural product.
Article Abstract
United in effort: The combined application of iminium (Im) and enamine (En) catalysts can effect a range of valuable asymmetric transformations including 1,2-hydroamination, -hydro-oxidation, and -amino-oxidation of olefins (see picture). An enantioselective organocascade catalysis was also applied in the synthesis of a complex natural product.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3057093 | PMC |
| http://dx.doi.org/10.1002/anie.200900220 | DOI Listing |
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