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Mercury is surrounded by a tenuous exosphere that is supplied primarily by the planet's surface materials and is known to contain sodium, potassium, and calcium. Observations by the Mercury Atmospheric and Surface Composition Spectrometer during MESSENGER's second Mercury flyby revealed the presence of neutral magnesium in the tail (anti-sunward) region of the exosphere, as well as differing spatial distributions of magnesium, calcium, and sodium atoms in both the tail and the nightside, near-planet exosphere. Analysis of these observations, supplemented by observations during the first Mercury flyby, as well as those by other MESSENGER instruments, suggests that the distinct spatial distributions arise from a combination of differences in source, transfer, and loss processes.
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http://dx.doi.org/10.1126/science.1172525 | DOI Listing |
Chempluschem
December 2024
Indian Institute of Technology Jodhpur, Chemistry, Jodhpur, 342037, Jodhpur, INDIA.
Herein, we present a distorted square pyramidal mercury complex, [HgII(L)Cl] (1), based on a quinoline-substituted formazan ligand LH[3-Cyano-1,5-(quinolin-8-yl)formazan], which was evaluated for its anti-bacterial activity in vitro. Complex 1 was prepared by refluxing 3-Cyano-1,5-(quinolin-8-yl)formazan ligand and mercury chloride(II) in equimolar quantity and was characterized utilizing a range of analytical methods, including single crystal X-ray diffraction (SCXRD) technique. The crystal packing in complex 1 has been elucidated using supramolecular investigations, which have shown the presence of fascinating Hg-Cl···Hg intermolecular spodium bonds of the order 3.
View Article and Find Full Text PDFEnviron Pollut
December 2024
Shandong Key Laboratory of Environmental Processes and Health, School of Environmental Science and Engineering, Shandong University, Qingdao 266237, China; Department of Chemistry & Biochemistry, Florida International University, Miami, Florida, 33199, United States.
Recent advancements in mercury (Hg) isotopic fractionation research have evolved from conceptual demonstrations to practical applications. However, few studies have focused on revealing fractionation fingerprinting for aqueous methylmercury (MeHg) photodegradation due to its sensitivity to natural organic matter (NOM). Here, the impact of NOM fractions with varying chemical properties on MeHg photodegradation kinetics and Hg isotope fractionation characteristics was investigated.
View Article and Find Full Text PDFInt J Hyg Environ Health
December 2024
Graduate School of Public Health, Seoul National University, Seoul, South Korea. Electronic address:
Several toxic metals have been associated with metabolic diseases like obesity and diabetes mellitus (DM) in humans. However, knowledge regarding the influence of many trace elements, especially in combination with essential elements is limited. This study aims to address this research gap by investigating the associations of both non-essential and essential inorganic trace elements in urine with DM and obesity, employing a group of postmenopausal women (n = 851) from the Korean Genome and Epidemiology Study (KoGES) cohort.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
College of Marine Geosciences, Ocean University of China, Qingdao 266100, PR China; Key Laboratory of Submarine Geosciences and Technology, MOE, Ocean University of China, Qingdao 266100, China.
As an important link of mercury (Hg) migration and transformation from land to ocean, rivers have been significantly influenced by anthropogenic activities, resulting in unpredictable environmental influences on the basin and offshore areas. In this study, the particulate Hg content of sediments in Xiaolangdi Reservoir (XLDR), Lijin Hydrological Station, and the Yellow River estuarine area during the water-sediment regulation scheme (WSRS) period in 2018 were analyzed, the characteristics and influencing factors of particulate Hg transport were explored. Our results revealed that the transport flux of particulate Hg into the sea during WSRS was 8.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2024
Istanbul Technical University, Department of Chemistry, 34469 Maslak, Istanbul, Turkey. Electronic address:
A novel probe NIR8 decorated with colorimetric, fluorometric, turn-on, and NIR properties was designed and synthesized using the chromenylium-cyanine platform for sensitive and selective quantification of Hg in real samples. The interaction between the probe and Hg resulted in the opening of the closed spirolactam ring of the chromenylium-cyanine platform, leading to a notable color shift from yellow to green. Concurrently, ratiometric spectral changes at 380 and 725 nm for UV-Vis and signal enhancement at 755 nm for fluorescence were observed.
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