A solution method of the Holstein-Biberman equation in the case of two-dimensional finite-size geometry by means of transformation of the integral operator to a four-dimensional matrix is presented. Using this matrix the array of two-dimensional eigenvalues and eigenfunctions of the radiation transport operator in the case of finite cylinder is determined. The exact two-dimensional characteristics have been compared with approximate functions determined as a combination of corresponding eigenvalues and eigenfunctions for the one-dimensional problems (cylinder of infinite length and slab). The spatiotemporal evolution of excited atom densities for two typical forms of the excitation source in a nonequilibrium plasma has been analyzed. The reasons for the distinct difference in the formation of spatiotemporal distributions of resonance and metastable atoms in the case when the spatial distribution of the excitation source does not coincide with the fundamental mode are discussed. Resonance atoms follow the excitation source while the diffusion effectively takes metastable atoms out from the excitation source. Rearrangement of metastable atoms to the fundamental mode during their decay lasts about one effective diffusion lifetime while the corresponding process for the resonance atoms takes much longer (several effective lifetimes). The differences are caused by the effective suppression of higher diffusion modes compared with radiation modes. The developed solution method treats the radiation transport processes at the same accuracy level as diffusion transport of other plasma components and it is suitable for a self-consistent modeling of nonequilibrium plasmas.
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http://dx.doi.org/10.1103/PhysRevE.79.036409 | DOI Listing |
ACS Biomater Sci Eng
January 2025
Advanced Materials Department, Jožef Stefan Institute, 1000 Ljubljana, Slovenia.
Characterization and formation of the biomineral aragonite structures of the Noah's Ark shell ( L.,1758) were studied from structural, morphogenetic, and biochemical points of view. Structural and morphological features were examined using X-ray diffraction, field-emission scanning electron microscopy, and atomic force microscopy, while thermal properties were determined by thermogravimetric and differential thermal analyses.
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
February 2025
CSIRO Division of Mineral Products, Port Melbourne, Victoria, Australia.
The crystallographic phase change from tetragonal litharge (α-PbO; P4/nmm) to orthorhombic massicot (β-PbO; Pbcm) has been studied by full-matrix Rietveld analysis of high-temperature neutron powder diffraction data collected in equal steps from ambient temperature up to 925 K and back down to 350 K. The phase transformation takes place between 850 and 925 K, with the coexisting phases having equal abundance by weight at 885 K. The product massicot remains metastable on cooling to near ambient temperature.
View Article and Find Full Text PDFNat Commun
January 2025
Center for High Pressure Science, State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, China.
Hydrous aluminosilicates are important deep water-carriers in sediments subducting into the deep mantle. To date, it remains enigmatic how hydrous aluminosilicates withstand extremely high temperatures in the mantle transition zone. Here we systematically investigate the crystal structures and chemical compositions of typical hydrous aluminosilicates using single-crystal X-ray diffraction, electron probe microanalyzer, and nanoscale secondary ion mass spectrometry.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
Center for High-Pressure Science, State Key Laboratory of Metastable Materials Science and Technology, School of Science, Yanshan University, Qinhuangdao, 066004, China.
Oxygen usually exists in the form of diatomic molecules at ambient conditions. At high pressure, it undergoes a series of phase transitions from diatomic O to O cluster and ultimately dissociates into a polymeric O spiral chain structure. Intriguingly, the commonly found cyclic hexameric molecules in other group VIA elements (e.
View Article and Find Full Text PDFInorg Chem
January 2025
School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, P. R. China.
It is especially essential to develop high-performance and low-cost nonprecious metal catalysts for large-scale hydrogen production. A large number of electrochemical catalysts composited by transition metal centers has been reported; however, it is still a great challenge to design and manipulate target electrocatalysts to realize high overall water-splitting activity at the atomic level. Herein, we develop totally new P-(Fe,V)-codoped metastable-phase β-NiMoO.
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