Severity: Warning
Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 143
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 143
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 209
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3098
Function: getPubMedXML
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
Severity: Warning
Message: Attempt to read property "Count" on bool
Filename: helpers/my_audit_helper.php
Line Number: 3100
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3100
Function: _error_handler
File: /var/www/html/application/controllers/Detail.php
Line: 574
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 488
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
A first representative of coordination polymers, built from polynuclear carboxylate bridged by mononuclear carboxylate, has been synthesised and structurally characterized. The compound [{Fe(3)O(HCOO)(6)}{Mn(HCOO)(3)(H(2)O)(3)}].3.5HCOOH crystallised in the hexagonal system (space group P6(3)), a = b = 12.369(5) A, c = 12.992(5) A, alpha = beta = 90 degrees , gamma = 120 degrees , V = 1721.4(12) A(3). The crystal structure is built from 2D layers, which are formed by the linking of trinuclear {Fe(3)O(HCOO)(6)}(+) units by mononuclear {Mn(HCOO)(3)(H(2)O)(3)}(-) bridges. These 2D honeycomb layers are connected by molecules of formic acid through a hydrogen bond network. The compound has the voids at the centre of the hexagons. These voids are filled by captured solvent molecules. Solvate molecules are also located between the 2D layers, linking them through a system of H-bonds. All these solvates can be easily removed and/or exchanged, which results in the formation of [{Fe(3)O(HCOO)(6)}{Mn(HCOO)(3)(H(2)O)(3)}].0.5HCOOH.H(2)O and [{Fe(3)O(HCOO)(6)}{Mn(HCOO)(3)(H(2)O)(3)}]. Magnetic properties of the compounds can be considered as the superposition of magnetism of Fe(3)O trinuclear units, for which magnetism is governed by the superexchange interaction between Fe(3+) spins (with one Fe-Fe superexchange parameter J) and the magnetism of spins of Mn(2+) ions, the interactions between these units can be taken into account by molecular field, zJ'. The destruction of the hydrogen bond network caused by evacuation of solvent molecules significantly modifies the overall magnetism. It was found that zJ' depends on the presence of solvent molecules in the structure.
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http://dx.doi.org/10.1039/b900359b | DOI Listing |
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