A DFT study of the single electron reduction and silylation of the U-O bond of the uranyl dication in a macrocyclic environment.

Chem Commun (Camb)

Laboratoire de Physique et Chimie des Nano-objets, INSA, Université Paul Sabatier, 135 avenue de Rangueil, 31077 Toulouse Cedex, France.

Published: May 2009

A DFT study of the reduction and silylation of the uranyl U-O bond in a macrocyclic complex shows the importance of the initial dipotassiation in THF solution, and a slightly downhill reaction pathway for the oxo group functionalisation.

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http://dx.doi.org/10.1039/b900571dDOI Listing

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