AI Article Synopsis
- A new method allows for the transformation of alkanes into carboxylic acids using just CO and water in a single reaction step.
- This process occurs under mild conditions, doesn't require metal catalysts or acid additives, and operates at low temperatures.
- Research shows that water plays a crucial part in the reaction, and the mechanisms involved have been studied using advanced techniques like radical-trap experiments and DFT analysis.
Article Abstract
A convenient and clean route to transform, in aqueous medium, various alkanes to carboxylic acids via single-pot carboxylation with CO and water, under mild conditions, has been achieved, proceeding efficiently and selectively even without any metal catalyst and any acid additive, at low temperatures; the relevant hydroxylating role of H(2)O and radical mechanisms are disclosed by radical-trap, H(2)(18)O and DFT studies.
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| http://dx.doi.org/10.1039/b900853e | DOI Listing |
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