Unexpected nucleophilic behaviour of free-radicals generated from alpha-iodoketones.

Chem Commun (Camb)

Université catholique de Louvain, Département de Chimie, Bâtiment Lavoisier, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium.

Published: April 2009

The unexpected nucleophilic reactivity of free-radicals generated from alpha-iodoketones is reported; two different procedures, either employing tin or the more environmentally acceptable ethylsulfone-based coupling reagent have been developed.

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Source
http://dx.doi.org/10.1039/b901943jDOI Listing

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