We present a new structure that combines a metal-dielectric-metal sandwich with a periodic structure to form a plasmon polariton photonic crystal. Three-dimensional finite-difference time-domain simulations show a clear bandgap in the terahertz regime. We exploited this property by adding a defect to the crystal, which produces a cavity with a quality factor of 23.3 at a wavelength of 3.45 microm. Despite the small Q factor, the ultrasmall sensing volume of 15 zeptoliters produces an extremely large Purcell constant of 4.8x10(6). Compared to photonic crystals with similar Purcell constant, the bandwidth is several orders of magnitude larger, or about 7 THz, ensuring high tolerances to manufacturing parameters, and environmental changes, as well as a high specificity owing to the possibility of broadband spectral fingerprint detection.
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http://dx.doi.org/10.1364/ol.34.001087 | DOI Listing |
Sci Rep
September 2024
Department of Optics and Photonics, National Central University, No. 300, Zhongda Rd., Zhongli, Taoyuan, 320317, Taiwan.
We refresh the design of zero-mode waveguides (ZMWs) by introducing metamaterials that makes the zeroth order resonant mode existence. Of particular importance, the resulting electromagnetic field exhibits nearly constant distribution but not a trivial solution of Maxwell's equation, showing great advantage to equalize the excitation rate of molecules throughout the waveguides. A closed form expression for the wave impedance is derived which is verified by the finite-difference time-domain simulations.
View Article and Find Full Text PDFMethods Mol Biol
July 2024
Department of Microbiology and Immunology, Peter Doherty Institute for Infection and Immunity, University of Melbourne, Melbourne, VIC, Australia.
ACS Nano
February 2024
Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States.
Black phosphorus (bP) is a promising material for mid-infrared (mid-IR) optoelectronic applications, exhibiting high performance light emission and detection. Alloying bP with arsenic extends its operation toward longer wavelengths from 3.7 μm (bP) to 5 μm (bPAs), which is of great practical interest.
View Article and Find Full Text PDFJ Am Chem Soc
February 2024
Molecular Biophysics Unit, Indian Institute of Science, Bangalore 560 012, India.
Molecular recognition events mediated by glycans play pivotal roles in controlling the fate of diverse biological processes such as cellular communication and the immune response. The affinity of glycans for their target receptors is governed primarily by the hydrogen bonds formed by hydroxyl groups decorating the glycan surface. Hydroxyl exchange rate constants are therefore vital parameters that report on glycan structure and dynamics.
View Article and Find Full Text PDFACS Nano
January 2024
Department of Physics and KI for the NanoCentury, Korea Advanced Institute of Science and Technology (KAIST), 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea.
Perovskite nanocrystals (NCs) have attracted increasing interest in the realization of single-photon emitters owing to their ease of chemical synthesis, wide spectral tunability, fast recombination rate constant, scalability, and high quantum yield. However, the integration of a single perovskite NC into a photonic structure has yet to be accomplished. In this work, the integration of a highly stable individual zwitterionic ligand-based CsPbBr perovskite NC with a circular Bragg grating (CBG) is successfully demonstrated.
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