Structure and reactivity of a unique Y-shaped tricoordinate bis(silyl)platinum(II)-NHC complex.

Angew Chem Int Ed Engl

Département de Chimie, Université catholique de Louvain, Place Louis Pasteur 1, 1348 Louvain la Neuve, Belgium.

Published: June 2009

Y not? A unique, three-coordinate Y-shaped bis(silyl)platinum(II) complex was isolated and characterized (see structure; C light gray, N blue, Si pink, Pt dark gray). DFT studies on a model system shed light on the nature of this unusual coordination mode for platinum(II).

Download full-text PDF

Source
http://dx.doi.org/10.1002/anie.200900435DOI Listing

Publication Analysis

Top Keywords

structure reactivity
4
reactivity unique
4
unique y-shaped
4
y-shaped tricoordinate
4
tricoordinate bissilylplatinumii-nhc
4
bissilylplatinumii-nhc complex
4
complex not?
4
not? unique
4
unique three-coordinate
4
three-coordinate y-shaped
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!